GCMS analysis results for sample AE03246, March 2002

NYC 9/11 Public Portal Document

Library Search Compound Report . Data File : C:\MSDCHEM\1\5973N\02MAR01\03246.D Vial: 1 Acq On : 1 Mar 2002 4:00 pm Operator: Sample : 508 scan Inst : Instrumen Mise : March 1, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\HP022102 .M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 10 2-Methoxy-3-hydrazinyl-pyra... Concentration Rank 14 R.T. EstConc Area Relative to ISTD R.T. 13.38 0.06 ug/L 40035 Naphthalene-d8 13.20 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 2-Methoxy-3-hydrazinyl-pyrazine 140 C5H8N40 000000-00-0 72 2 2,5-Cyclohexadiene-1,4-dione, 2,... 140 C6H404 000615-94-1 64 3 Pyridine, 4-nitro-, 1-oxide (CAS... 140 C5H4N2O3 001124-33-0 56 4 l-Oxetan-2-one, 4,4-diethyl-3-me... 140 C8H12O2 000000-00-0 50 Abundance Scan 886 (13.376 min): 03246. D (-) m/z 140.00 100.00% 140

5000

70 84 94 108

miz-> 01 ........ 54...Ionspila . ....... I.............. 30 40 50 60 70 80 !90 100 110 120 130 I | 140 "II 13.00 13.20 13.40 13.60 13.80 m/z 70.00 14.10% Abundance #35089:2-Methoxy-3-hydrazinyl-pyrazine 14.0

5000 42 13.00 13.20 13.40 13.60 13.80 54 68 m/z 94.10 10.96% 80 95 108 -121 01 ' ' i ' 1 ill II ll ■ ■ i ' ' TId mfz-> 30 40 50 60 70 80 90 100 110 120 130 140 Abundance #35122: 2,5-Cyclohexadiene-1,4-dione, 2,5-dihydroxy- $$ p-... VO 1 13.00 13.20 13.40 13.60 13.80 5000 m/ Z 84.00 10.22% 42 71 53 84 112

m/z-> O+ 1 ' i 1 1 ■ ■ i 30 40 mL. 50 60 70 | 94 ■ I ' I । 1 I ' I'| 80 1 । 1 1 1 1 । ' 1 1 1 । 1 1 । 1 । 1 * 90 100 110 120 130 140 ——— Abundance #35067: Pyridine, 4-nitro-, 1-oxide (CAS) $$ p-Nitropyridi... VO 13.00 13.20 13.40 13.60 13.80 m/z 96.10 10.03%

5000 39 110 51 45 63 124 84 94 0 -P --PPP ,......... Ji, —L TIT n/z—> 30 40 50 60 70 80 90 100 110 120 130 140 13.00 13.20 13.40 13.60 13.80

)3246.D HP022102.M Mon Mar 04 12:33:14 2002 Page 12

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