GCMS calibration table for TCLP method, Dec 2001

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Library Search Compound Report

Data File : M:\INSTRU~l\209\DATA\DEC1301\29522.D Vial: 21 Acq On : 14 Dec 2001 4:25 am Operator: 209 GALOS Sample : gems scan 12/7 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 15 Decanedioic acid, bis(2-ethylh Concentration Rank 9

R.T. EstConc Area Relative to ISTD R.T.

35.57 6.22 ug/1 1815270 Perylene-dl2 37.10

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Decanedioic acid, bis(2-ethylhexyl) 426 C26H50O4 000122-62-3 87 2 [1,1'-Biphenyl]-4-ol, 3-amino- 185 C12H11NO 001134-36-7 27 .3 Propanedioic acid, hexyl-, diethyl 244 C13H2404 005398-10-7 16 4 1-Decene, 2,4-dimethyl- 168 C12H24 055170-80-4 12 Abundance Scan 3325 (35.566 min): 29522 D (-) m/z 185.10 100.00% 1

1 185

57 5000 - 70 43 112 83 98 ■ ■ । ' 125 143 166 35.20 35.40 35.60 35.80 1 , 203,221 240 255268281 297 315, 0 ‘ I 11 J J - m/z 57.00 56.42% m/z-> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 'Abundance #55661: Decanedioic acid, bis(2-ethylhexyl) ester 185

57 "T 111 J 1" 5000 71 112 35.20 35.40 35.60 35.80 m/z 70 . " 39.50% 84 98 ......... | !J 125 143 166 203 298 316 ■ • ■ । • j < ' TIT rT’r i' • ■ ■ i ■ ' ■ ■ i'' ■' i ■ ■ ■ ■ i TT m/z-> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 Abundance #19199: [1.1-Biphenyl]-4-ol, 3-amino- 185 7 ‘I IiT 35.20 35.40 35.60 35.80 5000 m/z 71.05 37.86%

113 139 176 11 ■ ■ ■ i ■ ■ ■ ■ i ■ ■ • ‘ I ■ i' ■ ■ ■ । 11 i '' • ■ i ■ ■ ■ ■ i' ■'' i' ''' i m/z-> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 Abundance #32687: Propanedioic acid, hexyl-, diethyl ester • i > > ■ > i • i" 57 70 35.20 35.40 35.60 35.80 m/z 112.10 31.06% 5000 - 83 112

42 — 98 199 217 — d, 1 i ■ 1 ■ ' i 1 ’ I ‘1 ■ i' ■ ■ ■ r ■ ■' i '' ■ ■ i' ■ ■11' ' ■' i'' ■ ■ i ■ ' ■ ' i ■'' ■ i ■ ■ ■ ■ i ' ■' ' r ■ 1 1 ■ '-■ | 1 ■ ' i ' 1 1 ' l ' m/z-> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 35.20 35.40 35.60 35.80

29522.D GCMS1126.M Tue Jan 08 10:55:02 2002 Page 15

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