GCMS calibration table for TCLP method, Dec 2001

NYC 9/11 Public Portal Document

Library Search Compound Report

Data File : M:\INSTRU-l\209\DATA\DEC1301\29522.D Vial: 21 Acq On : 14 Dec 2001 4:25 am Operator: 209 GALOS Sample : gems scan 12/7 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L

Peak Number 14 Phosphonic acid, phenyl-, bis( Concentration Rank 8

R.T. EstConc Area Relative to ISTD R.T.

32.41 6.27 ug/1 9815970 Chrysene-dl2 33.02

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Phosphonic acid, phenyl-, bis(trime 302 C12H2303PSi2 042449-24-1 16 2 Androstane/3,6,17-trione, (5.beta.) 302 C19H2603 026991-58-2 10 3 Androstane-3,6,17-trione, (5.alpha. 302 C19H2603 002243-05-2 10 . 4 [1,11-Biphenyl]-3,3'-dicarboxaldehy 302 C16H1406 002092-49-1 10 Abundance Scan 2981 (32.408 min): 29522.D (-) m/z 287.10 100.00% 287

302 5000 209 105 165 223 77 91 TIE

pas-#—’- 12186.239253I TTT 2711 1 I 340 Ah 4 | . 128 147 32.00 32.20 32.40 32.60 32.80 0 ■ i ■ ■ m/z 302.10 61.91% m/z-> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 Abundance #43026: Phosphonic acid, phenyl-, bis(trimethylsilyl) ester 287

5000 I",1 । ■11 ■ । ■ ■ ■ ■ । ■ ■

32.00 32.20 32.40 32.60 32.80 — 211 302 m/z 209.00 47.51% 73 195 । 121115 . I ! 271 ' ' ■ i ■'' ■ TTTTTTTrT p > , . । . r. . । m/z-> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 Abundance #43139: Androstane-3,6,17-trione, (5.beta.)- 302 T’’ , -01111111 123 32.00 32.20 32.40 32.60 32.80 5000 m/ Z 04.95 34.61% 67 206 93 108 149 | 191 ; T’TTTTTTTTTTT1 TTTTET Ti I I 233 269 287 I'' I •• ’ ’ i " " i " '' l " '' l " ■' i' ■'' I' ‘' l '' m/z-> 40 60 80 . 100 120 140 160 180 200 220 240 260 280 300 320 340 Abundance #72822: Androstane-3,6,17-trione, (5.alpha.)- V 123 273 302 32.00 32.21 32.40 32.60 32.80 m/z 223.10 27.42% 137 108 207 5000 - 287 231245 m/z—> • । ■ ■ ■ ■ । • ■ ■ • । • 40 60 80 _... . LL TT’m T‘"111‘‘111—TEITCCOITTTTITTTTTTT । I । । 1 । T 1T 1 I '■'■'-'Tri it" 1 1 I ' 1 1 1 1 1 1 100 120 140 160 180 200 220 240 260 280 300 320 340 32.00 32.20 32.40 32.60 32.80

29522.D GCMS1126.M Tue Jan 08 10:54:56 2002 Page 14

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