GCMS calibration table for TCLP method, Dec 2001

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Data File : M:\INSTRU~1\209\DATA\DEC1301\29522.D Vial: 21 Acq On : 14 Dec 2001 4:25 am Operator: 209 GALOS Sample : gems scan 12/7 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 13 2H-Pyran-2-one, 6-[2-(1,3-benz Concentration Rank 10

R.T. EstConc Area Relative to ISTD R.T.

32.24 5.73 ug/1 8969950 Chrysene-dl2 33.02

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 2H-Pyran-2-o:ne, 6-[2-(1,3-benzodiox 302 C16H14O6 052525-96-9 11 2 Methanone, 1,4-dimethyl-7-(1-methy 302 C22H220 039665-56-0 10 3 Androstane -3,6,17-trione, (5.alpha. 302 C19H2603 002243-05-2 10 4 [1,11-Biphenyl]-3,31-dicarboxaldehy 302 C16H14O6 002092-49-1 10 Abundance Scan 2963 (32.243 min): 29522.D (-) m/z 287.10 100.00% 287

5000 209 105 165 77 1 1 I ' ' i 1 ' 1 ’ i ' ‘

1m/z-> , 0-mtn 51 4a 4 A,L21. 128 14 239 269 3)4 326 397 TTNTTT ■ ■ p •" i' " ' i " " r 1 " r ■ ■' r ■ 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380 400 32.00 32.20 32.40 32.60 m/z 302.10 61.03% Abundance #43076: 2H-Pyran-2-one, 6-[2-(1,3-benzodioxol-5-yl)ethenyl] 302 89 175 145 i ■ ' ■ ' i 1 ■ 5000- 69 32.00 32.20 32.40 32.60 117 228 259 m/z 209.00 46.41% ...................... I — 1 ।।11«1111 i|! i n । ri I' • •' I miz-> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380 400 Abundance #43214: Methanone. [1,4-dimethyl-7-(1-methylethyl)-2-azulen 302 77 105 _____ _ < ' ' 1 1 ' • ' I ’ ' I ' ■ ' 1 1 1 1 32.00 32.20 32.40 32.60 5000- ............ : ■ 5 29.93% 165 197 | 216 244 273 TTe y-m-q-m-r1′11′1′21111 , Ti ' i" " i । । i f 11 > f f i | r. ri । T’T’TT m/z-> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380 400 Abundance #72822: Androstane-3,6,17-trione, (5.alpha.)- V Tim 123 273 302 32.00 32.20 32.40 32.60 m/z 223.10 28.40% 207 5000 149 231

1" i" " r "' r ■" r1" i" i'r "' r'1' i 251 1 ll. ..I TUEE-,"TTTT"TTrT‘‘"TI ______ ■ 1 I • 1 >I • I’ i ■ ■ ' ' i ' ' m/z-> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380 400 32.00 32.20 32.40 32.60

29522.D GCMS1126.M Tue Jan 08 10:54:51 2002 Page 13

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