GCMS calibration table for TCLP method, Dec 2001

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Library Search Compound Report

Data File : M:\lNSTRU~l\209\DATA\DEC1301\29522.D Vial: 21 Acq On : 14 Dec 2001 4:25 am Operator: 209 GALOS Sample : gems scan 12/7 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L

Peak Number 12 Ethyl 4-acetylbenzoate Concentration Rank 4

R.T. EstConc Area Relative to ISTD R.T.

32.20 22.14 ug/1 34682300 Chrysene-dl2 33.02

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Ethyl 4-acet benzoate 192 C11H1203 038430-55-6 32 2 Phenol, 2,2/ -methylenebis[6-(1,1-di 340 C23H3202 000119-47-1 14 3 1, 3-Benzodioxol-2-one, 5-(l,l-dimet 192 C11H1203 054815-21-3 12 ■ 44(1H)-Pteridinone,2-amino-7-methyl177C7H7N50 Abundance Scan 2958 (32.197 min): 29522.D ( ) 013040-58-9 100.00% 12 1 7

5000 149 121 340 57 91 1 ■ T‘ ■■■!■■ 31.80 32.00 32.20 32.40 32.60

m/z-> 32,,47444lu4lL TTCTmT 209 228 247 265 2 84 307 396 T" '11'1'1 i' 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380 400 m/Z 161.00 72.48% Abundance #20691: Ethyl 4-acetylbenzoate 1 7

5000 147 I ’ ' ' ' I ' ' ■ i1 ■ i ■ ■

31.80 32.00 32.20 32.40 32.60 76 104121 m/z 164.00 48.04% 111111 t t 1111 ■ k 11 i i ■ ip rn । TTTTT I‘u‘I1‘EuI0910111110101I0U2011—11—0*O—OOUITT m/z-> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380 400 Abundance #48222: Phenol, 2.2'-methylenebis(6-(1.1-dinietfiylethyl)-4-rn 177 340 31.80 32.00 32.20 32.40 32.60 5000 149 ! m/z 149.00 47.96% 121 284 i i J I pTTTyrrrrprrrrj-TT i •" ' i" " i" " i" " i ■ " ■ r " ■ i 11' ■1 l" • ’ I r1" i" miz-> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380 400 Abundance #20701: 1,3-Benzodioxol-2-one, 5-(1,1-dimethylethyl)- 1 7 31.80 32.00 32.20 32.40 32.60 m/ z 34 0.20 .0 25 .'91% 5000-

105 51 77 133 I || , I 150 134 . ............. — 111111 T’T 111" i " " i" " i' " 'I ■' II"IEIE—u—u—u——m““Eu[" 1 1 1 1 1 1 ' 1 1 1 m/z~> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380 400 31.80 32.00 32.20 32.40 32.60

29522.D GCMS1126.M Tue Jan 08 10:54:45 2002 Page 12

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