GCMS calibration table for TCLP method, Dec 2001

NYC 9/11 Public Portal Document

Library Search Compound Report

Data File : M:\INSTRU~l\209\DATA\DEC1301\29522.D Vial: 21 Acq On : 14 Dec 2001 4:25 am Operator: 209 GALOS Sample : gems scan 12/7 Inst : GC/MS 209 Mise : Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L

Peak Number 11 Pyrazine, tetramethyl- Concentration Rank 17

R.T. EstConc Area Relative to ISTD R.T.

25.30 1.04 ug/l 515100 Phenanthrene-dlO 24.98

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Pyrazine, tetramethyl- 136 C8H12N2 001124-11-4 56 2 2-Butyne 54 C4H6 000503-17-3 9 3 2H-Pyran, 2,5-diethenyltetrahydro- 138 C9H140 025724-33-8 9 4 Propanenitrile, 3,3'-oxybis- 124 C6H8N20 001656-48-0 9 Abundance f Scan 2207 (25.303 min): 29522.D (-) m/z 53.95 100.00% 54

136 5000 42

66 83 J „ 95 1 09119 । 147157 176 203 —। A _ ) V _ 25.00 25.20 25.40 25.60 | ... I40 II — -[-T-r-T-r- | I I I I | I I I , j -T I r I | m/z 136.00 65.80% m/z--> 20 60 80 100 120 140 160 180 200 Abundance #65704: Pyrazine, tetramethyl- 54

42 136 ) 5000- ' ■ ■ l ‘ ■ ■ ■ ] ■ '

25.00 25.20 25.40 25.60 27 m/z 42.05 39.13% 15 I ... 80 95 .. 121 , । ■ ■ ■ 1 । ■ ' ■ ■ । ■ ■ ' ■ । ■ ■ ■ ■ । miz—> 20 40 60 80 100 120 140 160 180 200 'Abundance #64: 2-Butyne 54 ■ ' i ■ ' 25.00 25.20 25.40 25.60 5000- 27 m/z 82.95.13.07% 39

i ' ' ' ' i ' ' ' ■ i ' ' ' ' i 1 ' ' ' i ' ■ ' ■ i ■ • ' ■ i ' ■ ■ ■ i ' ■ • ' i ' ' • ■ i ■ ■ ■ ■ i m/z-> 20 40 60____ 80 100 120 140 160 180 200 'Abundance #6996: 2H-Pyran, 2,5-diethenyltetrahydro- 54 25.00 25.20 25.40 25.60 m/z 81.95 9.00% 5000-

67 79 97 miz-> ■ i

20 ■ • ■ 1 i

40 Il _ 97 109 ............... I I I » . .J . « I., . I I I I I I I I I I 1 I t I I I . . I . . . . I .... I 60 80 100 120 140 160 180 200 4 25.00 25.20 25.40 25.60

29522.D GCMS1126.M Tue Jan 08 10:54:38 2002 Page 11

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