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GCMS calibration table for TCLP method, Dec 2001

Machine-extracted title · confidence 100%

Quality reviewed GCMS calibration data listing surrogate compounds and retention times from December 14, 2001.

NYC-WTC_000036729–000036751

Folder label: “GCMS X 12/7/01 A 1/2/02

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Scanned page image, NYC-WTC_000036743
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NYC 9/11 Public Portal Document

Library Search Compound Report

Data File : M:\INSTRU~1\2O9\DATA\DEC13O1\29522.D Vial: 21. Acq On : 14 Dec 2001 4:25 am Operator: 209 GALOS Sample : gems scan 12/7 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L

Peak Number 10 Permethrin Concentration Rank 7

R.T. EstConc Area Relative to ISTD R.T.

25.12 8.89 ug/1 4401420 Phenanthrene-dl0 24.98

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Permethrin/ 390 C21H20C12O3 052645-53-1 64 2 Cyclopropanecarboxylic acid, 3-(2,2 390 C21H20C12O3 051877-74-8 45 3 Hydrazinecarboxamide , 2 - (2,6-dimeth 183 C9H17N3O 057174-11-5 43 4 Benzenemethanol, . alpha .-methyl-. al 198 C14H140 000599-67-7 38 Abundance Scan 2187 (25.119 min): 29522.D (-) m/z 182.95 100.00% 183

5000 165 ----- . 199 221 51 77 . 103121 141. 24.80 25.00 25.20 25.40 ------ 11 i~~i 'i 11111111111111111111111111TITTTTTTTTTTTT 0 m/z 198.05 36.45% miz-> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380 Abundance .... ............... #74166: Permethrin “ 183

5000 24.80 25.00 25.20 25.40 163 m/z 165.00 21.95% 77 II L TTTTTTTTpnnT7TTTTp-rrTTTY^^ .II,. 127 l1' " i i" " i" " i 257 TUAODUTTTTTTTTTu 311 354 390 m/z-> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380 Abundance #53082: Cyclopropanecarboxylic acid. 3-(2,2-dichlorovinyl)- 183 i — 24.80 25.00 25.20 25.40 5000 m/z 184.00 14.68% 163 91 127 | 1109, ...... r '1' i'' ■' i' ‘" i" " r ' " i" '' i'' " i i" " i ‘ " • I ’' "I T’TTIT I‘"‘IOICOUIIITEITTT m/z—> 4Q 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380 Abundance #18580: Hydrazinecarboxamide, 2-(2,6-dimethylcyclohexyliden J 1. 183 24.80 25.00 25.20 25.40 m/z 77.05 11.06% 126 61 5000 108

m/z—> TTpT-rrp-rrrprr TT ।। 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380 ।111 11 i i । । । TTTTT’TT 111 111 j 11111 1 —24.80 25.00 25.20 25.40

29522.D GCMS1126.M Tue Jan 08 10:54:33 2002 Page 10

NYC-WTC_000036743

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NYC-WTC_000036743Source: NYC Law Department, mirrored locally

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