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GCMS blank analysis results for sample AE11379, May 21, 2002

Machine-extracted title · confidence 95%

Laboratory report showing GCMS blank analysis for sample AE11379 conducted on May 21, 2002, with results below minimum reporting levels.

NYC-WTC_000025054–000025071

Folder label: “GCMS X 5/15/02 A 5/17/02

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NYC 9/11 Public Portal Document Library Search Compound Report

Data File : C:\MSDCHEM\1\DATA\051702\0515LB.D Vial: 16 Acq On : 18 May 2002 1:49 am Operator: Mclean Sample : 5/15 eh Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e

Quant Method : C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L

Peak Number 3 Pyrazine, tetraethyl- Concentration Rank 10

R.T. EstConc Area Relative to ISTD R.T.

22.58 0.29 ug/L 418745 Phenanthranene-dl0 22.95

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Pyrazine, tetraethyl- 192 C12H20N2 038325-19-8 45 2 Phenanthrene, 9-methyl- 192 C15H12 000883-20-5 42 3 4-Hydroxy-3,5-dimethylcinnamic acid 192 C11H1203 1000132-15-8 39 4 2-Imidazolidinone, 1-methoxy-3-p... 192 C10H12N2O2 052420-43-6 38 Abundance Scan 3319 (22.580 min): 0515LB.D (-3306) (-) m/z 192.10 100.00% 192

5000

— — 82। 96 . 146 160 ...... R.... A 22.20 22.40 22.60 22.80 23.00 42 70 118 I । 0 —TTTTPTHTTTHTH - m/z 191.00 22.47% m/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #80990: Pyrazine, tetraethyl- 192 177

5000 41 22.20 22.40 22.60 22.80 23.00 67 m/z 193.00 13.94% 53 29 81 149 163

m/z-> 0 - T+ 93 TTpmhtptlI -7 .II 4 Tpr 107 121 133 20 30 40 50 60 70 80 90 100 110 120 130'140 150 160 170 180 190 200 Abundance #81033: Phenanthrene, 9-methyl- 192 TIT 22.20 22.40 22.60 22.80 23.00 5000 m/z 146.10 13.51%

96 165 i । 29 39 51 63 74 33 J 115 126 139 152 ,| 176 JR 0 11 ■1111'11' r 1 r 11' r''111 ■ri 111, ■11 ■11 ‘ r " ' r ■' ■ r ■ ■111'1 ''|111 T*11111,1111 rll i111 TTT /z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #81030:4-Hydroxy-3,5-dimethylcinnamic acid 192 ,.... 4 22.20 22.40 22.60 22.80 23.00 m/z 96.20 12.39%

5000

89 175 63 145 45 , 105 117 il 77 0 ------44 144iTTn 135 1, 163 I'l'l 111 rhtt 111 ll‘l 111 I’ll 11111111 I .......... , /z—> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 22.20 22.40 22.60 22.80 23.00

0515LB.D 050102.M Tue May 21 11:58:12 2002 Page 6

NYC-WTC_000025063

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NYC-WTC_000025063Source: NYC Law Department, mirrored locally

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