GCMS calibration table for TCLP method, Dec 2001

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Library Search Compound Report

Data File : M:\INSTRU~1\209\DATA\DEC1301\29522.D Vial: 21 Acq On : 14 Dec 2001 4:25 am Operator: 209 GALOS Sample : gems scan 12/7 Inst : GC/MS 209 Mise : Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L

Peak Number 8 Naphthalene, 1,6-dimethyl-4-(1 Concentration Rank 5

R.T. EstConc Area Relative to ISTD R.T.

24.00 .15.44 ug/1 7647250 Phenanthrene-dl0 24.98

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Naphthalene, 1, 6-dimethyl-4-(1-meth 198 C15H18 000483-78-3 72 2 Cyclopropanecarboxylic acid, 3-(2,2 390 C21H20C12O3 051877-74-8 53 3 Benzene, ethylphenoxy- 198 C14H140 054852-74-3 47 4 Azulene 1,4-dimethyl-7-(1-methylet 198 C15H18 000489-84-9 46 'Abundance Scan 2065 (23.999 min): 29522.D (-) ‘ m/z 182.9,5 100.00% I 183

5000 - 198 165 77 91 ' ' i ■ ' ' ' i 1 ' i ■ ■ ■ • i ■ 1

mlz-> 0 . 39 51 TIT I - ---- 40 63 I 103 — 60 120,141 153 31141— 80 100 120 140 160 + 180 । TTrun I”. t . I I . I I . I 200 221 233 250 220 240 23.60 23.80 24.00 24.20 24.40 m/z 198.05 45.26% 'Abundance #22544: Naphthalene, 1,6-dimethyl-4-(1-methylethyl)- 183

5000 198 23.60 23.80 24.00 24.20 24.40 153 168 m/z 165.00 26.30%

m/z--> -............. 141,4— 40 60 80 10C 120 140 160 180 200 220 ■ ■ i ' ■ • ■ i • ■ ■ > i • • ■ • i ’ ■ ■ • j 240 Abundance #53082: Cyclopropanecarboxylic acid. 3-(2,2-dichlorbvinyl)- 183 I 23.60 23.80 24.00 24.20 24.40 5000- m/z 184.00 14.28% 163

■ ■ i ■ ■ • ■ i • < • ■ । 77 91 115 127 .......................... .... ■ ■ । ■ • ■ 153 1 ' i 1 ' • i ‘ । • TII 1 1 1 ' t m/z-> 40 60 80 100 120 140 160 180 200 220 240 Abundance #22520: Benzene, ethylphenoxy- ..... ...................... ----- 183 23.60 23.80 24.00 24.20 24.40 198 m/z 91.00 14.22% 5000 -

77 51 | • 1 105 ,l, 155165 I ,I | ‘ ' i 1 1 1 ‘ i ‘ ' i ‘ ' i - /.V, N , AA miz-> 40 60 80 100 120 140 160 180 200 220 240 23.60 23.80 24.00 24.20 24.40

29522.D GCMS1126.M Tue Jan 08 10:54:22 2002 Page 8

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