GCMS calibration table for TCLP method, Dec 2001

NYC 9/11 Public Portal Document

Library Search Compound Report

Data File M:\INSTRU~1\2O9\DATA\DEC13O1\29522.D Vial: 21 Acq On 14 Dec 2001 4:25 am Operator: 209 GALOS Sample gems scan 12/7 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L

Peak Number 7 Benzoic acid, thio-, isopropyl Concentration Rank 3

R.T. EstConc Area Relative to ISTD R.T.

23.10 49.69 ug/1 24608000 Phenanthrene-dl 0 24.98

Hit# Of 5 Tentative ID MW MolForm CAS# Qual

1 Benzoic acid, io-, isopropylidene 192 C10H12N2S 020185-02-8 38 2 5-Methyl-2,4-di isopropylphenol 192 C13H20O 000000-00-0 38 3 1,3 -Benzodioxol-2-one, 5-(l,l-dimet 192 C11H12O3 054815-21-3 30 4 Methyl 4-pert-butylbenzoate 192 C12H1602 026537-19-9 27 Abundance 77 Scan 1967 (23.100 min): 29522.D (-) m/z 177.0,5 100.00%| 1 7

191 5000 163 248 41 55 91 149 . 233 205 219 .I) ' . ' i I 107 121 135 ' ' 1 11 11 I ' ' 22.80 23.00 23.20 23.40 —' a 1 4 144all—ulL,+l ll, a L + , 1., . . ।, ... ।. TTT m/ z 191.0,0 56.96% m/z--> 40• 60 80 100 120 140 160 180 200 220 240 Abundance #69292: Benzoic acid, thio-, isopropylidenehydrazide 177

5000 • ■ । 1 1 ...... ‘I I I I I I I I 22.80 23.00 23.20 23.40 192 m/z 163.00 47.67% r ' I1' — I ' , L . 92 104 , 121 135 ......... \.................. 42 56

m/z-> 40 60 80 100 120 140 160 180 200 220 240 Abundance #20799: 5-Methyl-2.4-diisopropyiphenol 177

22.80 23.00 23.20 23.40 5000 m/z 248.10 44.14% 192 135 80 -ip? 121 149 161 m/z-> 40 60 80 100 120___140 160 180 200 220 240___ _ Abundance #20701: 1,3-Benzodioxol-2-one, 5-(1,1-dimethylethyl)- ’ ’ I • < » • I ■ 1 i > • • ■ i • ■ 177 22.80 23.00 23.20 23.4 m/ Z 41.05 31.03% 5000

105 192 77 133 . „ 51 62 11 89 | 149 rnmn ■ । ■ i > ■ ■ > । > • ■ ■ । m/z-> 40 60 80 100 120 140 160 180 200 220 240 22.80 23.00 23.20 23.40

29522.D GCMS1126.M Tue Jan 08 10:54:17 2002 Page 7

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