GCMS analysis comments, sample AD29230, Dec 2001

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Library Search Compound Report

Data File : C:\HPCHEM\1\DATA\DEC1001\29230.D Vial: 18 Acq On : 11 Dec 2001 3:18 am Operator: 209 GALOS Sample : gc/ms scan 12/3 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params; LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 2 2-Propanone, 1,1,1-trichloro- Concentration Rank 4

R.T. EstConc Area Relative to ISTD R.T.

7.74 0.52 ug/1 151995 1,4-Dichlorobenzene-d4 11.67

Hit# Of 5 Tentative ID MW MolForm CAS# Qual

1 2-Propanone, 1,1,1-trichloro- 160 C3H3C13O 000918-00-3 23 2 N-Acetylpyrrolidone 127 C6H9NO2 000932-17-2 9 3 4-Penten-2-one 84 C5H80 013891-87-7 9 4 1-Fluorononane 146 C9H19F 000463-18-3 9

L Abundance Scan 294 (7.745 mln): 29230.D (-) m/ z 443.00 100.00% 43

5000 111nt 7.40 7.60 7.80 8.00 ‘‘11111111111’ 1H 37 , , 150. , 61, 75 , 33, ,, 87,103, ,,, 1914 — m/z 124.85 9.33% miz-> 10 20 30 40 50 60 70 80 90 100 110 120 130 Abundance #12247:2-Propanone, 1,1,1-trichloro- 43

5000 Tt 7.40 7.60 7.80 8.00 15 m/ Z 82.9.5 7.04% 35 ,49 85 97 i IT TT 1 > 1 1 | l J I I j l l'l I | I I T‘ i . . . j . . 117। I125 .'1'. I . . 11 • ■ ■ i • 1 ■ • i ■ ‘ i ■ miz-> 10 20 30 40 50 60 70 80 90 100 110 120 130 Abundance #4732: N-Acetylpyrrolidone 43 AAA 7.40 7.60 7.80 8.00 5000- m/z 126.90 6.81% 99 127 56 86 30 69 112 -PPPP ‘ I ■ ■ ‘ ' i ' • ' ■ I ' ■ ■ ■ i ■ ‘ — i ' • ■ ' i ' ' ' ■ i ■ ■ ‘ ■ i ' ■ ■ ■ i ■ ■ miz-> 10 20 30 40 50 60 70 80 90 100 110 120 130 Abundance #555: 4-Penten-2-one 1■i■'1' i ■ •1 ■ । ■1111 ■ ■111 43 7.40 7.60 7.80 8.00 m/z 96.95 6.76% 5000

15 84 27 371, 53 69 111'11111 T +TT I ‘ ‘ ' I ' ‘ ‘ ‘ I ‘ mmTI 1 ' I 1 1 ‘ 1 I 11 ‘ I ‘ ‘ ‘ I ‘ ‘ ' I ' m/z—> 10 20 30 40 50 60 70 80 90 100 110 120 130 7.40 7.60 7.80 8.00

29230.D GCMS1126.M Fri Dec 14 16:08:56 2001 Page 2

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