GCMS analysis comments, sample AD29138, Dec 2001

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Library Search Compound Report

Data File : C: \HPCHEM\ 1 \DATA\DEC1001\29138.D Vial: 38 Acq On : 12 Dec 2001 12:45 am Operator: 209 GALOS Sample : gc/ms scan ll/30a Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 2 2-Propanone, 1,1,1-trichloro- Concentration Rank 2

R.T. EstConc Area Relative to ISTD R.T.

7.75 0.60 ug/1 173081 1,4-Dichlorobenzene-d4 11.68

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 2-Propanone, 1/1,1-trichloro- 160 C3H3C130 000918-00-3 38 2 5-Hexen-2-om 98 C6H10O 000109-49-9 9 3 2-Propanone/ 1,1-dichloro- 126 C3H4C120 000513-88-2 9 4 N-Acetylpyrrolidone 127 C6H9NO2 000932-17-2 5 Abundance Scan 294 (7.746 mln): 29138.D (-) m/z 43.05 100.00% 43

5000 —r-r-j-TBnnn.n-T TTTTTgnsi 97 125 7.40 7.60 7.80 8.00 1 53 63 nmPPt +t’ ' ' T 35 82 11 119 I ■ | VP. m/z 124.85 10.98% miz-> 10 20 30 40 50 60 70 80 90 100 110 120 130 Abundance #12247: 2-Propanone, 1,1,1-trichloro- 43 T11—111th11 5000 > » I ■ * • ■ । • 7.40 7.60 7.80 8.00 15 m/z 96.95 7.33% | 35 49 85 97 117 1?5 ‘ ■ i •»• • i • • ■' i • TImTTTgrt miz-> 10 20 30 40 50 60 70 80 90 100/110 20 30 Abundance ” ... #1291: 5-Hexen-2-one 43 T 1 7.40 7.60 7.80 8.00 5000 m/z 126.90 6.85% 55 27 83 98 37 69 TIpua—t—uu——tum*—2O—I50 TIBTRTtggT m/z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 Abundance.... #4368: 2-Propanone, 1,1-dichloro- 1 • i • • • ■ i ■ ■ ■ i ' 1 ■ ■ i • ■ ■ ‘ i • 43 7.40 7.60 7.80 8.00 m/z 46.90 5.96% 5000

15 27 37 49 63 76 83 93 Mw/MWAa 1 i''1 ■ i ■ • ■ i • ■ • • i1 *WDTmpoppa]meTIT TI—2EEDOIIEDA2/1ET55}.1 m/z~> 10 20 30 40 50 60 70 80 90 100 110 120 130 7.40 7.60 7.80 8.00

29138.D GCMS1126.M Wed Dec 12 15:55:44 2001 Page 2

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