GCMS analysis comments for sample AD29139, Dec 17 2001

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Library Search Compound Report

Data File : C: \HPCHEM\ 1 \DATA\DEC1001\29139.D Vial: 11 Acq On : 10 Dec 2001 8:30 pm Operator: 209 GALOS Sample : gc/ms scan 11/30 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 2 2-Propanone, 1,1,1-trichloro- Concentration Rank 3

R.T. EstConc Area Relative to ISTD R.T.

7.74 0.59 ug/1 143721 1,4-Dichlorobenzene-d4 11.67

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 2-Propanone, 1,1,1-trichloro- 160 C3H3C130 000918-00-3 28 2 2-Propanone, 1,1-dichloro- 126 C3H4C120 000513-88-2 12 3 4 -Penten-2-one 84 C5H80 013891-87-7 9 4 2-Acetylthiazole 127 C5H5NOS 024295-03-2 9 Abundance Scan 294 (7.740 min): 29139.D (-) m/z 43.05 100.00% 43

5000 ■ « J * l » T J « » I » |TT 1 1 | Inf 7.40 7.60 7.80 8.00 miz-> 4950 576063 70 74 8082% ' 1111111 1 1 11111 10 20 30 40 37 11 i . > j . . . . ,Ti . . । i i i i । rri । । ■ । it । i । । । । । i TTTT 90 100 110 120 130 । i i m/z 124.85 10.63% Abundance #12247:2-Propanone, 1,1,1-trichloro- 43

— 5000 7.40 7.60 7.80 8.00 15 m/z 81.85 8.03% 1 35 49 85 97 117 125 <. 11... 1111111 i'i । j । Immmm ITHTTTTOINIIITTTTTTTT m/z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 Abundance #64841; 2-Propanone. 1,1-dichloro- 43 1112700. ‘ ‘ • I 1 1 1 1 I 7.40 7.60 7.80 8.00 5000 m/z 46.8.5 6.58%

27 36 49 63 83 91 126 TII1m9111SrotTrnu—)u—tTnourpunuVuptfTITIr miz-> 10 20 30 40 50 60 70 80 90 100 110 120 130 Abundance #555: 4-Penten-2-one 43 7.40 7.60 7.80 8.00 m/z 82.85 6.02% 5000

15

m/z-> 10 20 27 30 — 374 ■ i' ' ' ' i ■ 40 50 53 60 69 70 84 TI——1mmmTmmm 80 fr ’1’1111111111 90 100 110 120 130 7.40 7.60 7.80 8.00 T

29139.D GCMS1126.M Wed Dec 12 16:07:05 2001 Page 2

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