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GCMS comments for sample AD26473 detecting N,N-dimethylbenzenesulfonamide

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DEP lab report dated December 10, 2001, identifying N,N-dimethylbenzenesulfonamide at 0.49 ug/L in sample AD26473.

NYC-WTC_000031636–000031649

Folder label: “GCMS X 11/5/01 A 12/1/01

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NYC 9/11 Public Portal Document

Library Search Compound Report Data File : C:\HPCHEM\1\DATA\NOV3001\26473.D Vial: 9 Acq On : 30 NOV 2001 7:30 pm Operator: GALOS Sample : gc/ms unknown 11/3 Inst : GC/MS Ins Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\NP112701.M (RTE Integrator) Title : 208 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 5 Benzenesulfonamide, N,4-dimeth Concentration Rank 7 R.T. EstConc Area Relative to ISTD R.T. 23.57 0.49 ng/uL 229923 Phenanthrene-dl0 25.19 it# of 5 Tentative ID MW MolForm CAS# Qual 1 Benzenesulf onamide, N, 4-dimethyl- 185 C8H11NO2S 000640-61-9 83 2 Benzene, 1 -methyl -2 -nitroso- 121 C7H7NO 000611-23-4 38 3 Benzeneethanamine 121 C8H11N 000064-04-0 37 4 Benzaldehyde, 3-benzyloxy-2-fluoro- 260 C15H13FO3 000000-00-0 32 Abundance Scan 2042 (23.565 min): 26473.D (-) m/ z 91.05 100.00% 91

5000 65 185 155 39 .. 121 23.20 23.40 23.60 23.80 24.00 51 51 1 78 1 ...108..— ......... I, TITMTITT 1' i"'' i" m/z—> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 m/z : I I I i I I I I : i I : I I II I I k I' 65.10 25.81% Abundance #19121: Benzenesulfonamide, N,4-dimethyl- 91

5000 23.20 23.40 23.60 23.80 24.00 30 65 155 185 m/z 185.00 19.75% 121 48 139 108 , — 1 I . . I l'l . . . . I I l'l I I I I I I [ I I 1 I I 1 l'l I I I I miz-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 Abundance #64592: Benzene, 1-methyl-2-nitroso- 65 91

23.20 23.40 23.60 23.80 24.00 5000 m/z 155.00 17.53% 121 106 - ... || ..।.I.।.11l i.।....j।»।।. “ i “'1111 m/z—> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 ....................—.......................... Abundance #64604: Benzeneethanamine 33 23.20 23.40 23.60 23.80 24.00 m/z92.05 17.33% 5000 91 65

m/z—> ....... LZ .. L TIUImdmmuOmpg | 11111TIITT 11111'l 11111'l 11111'l'l 11 20 30 40 50 60 70 .. 104 121 |, 80 90 100 110 120 130 140 150 160 170 180 190 ‘I T T T IT 23.20 23.40 23.60 23.80 24.00

26473.D NP112701.M Tue Dec 04 10:45:15 2001 Page 5

NYC-WTC_000031646

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