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GCMS analysis results for sample AE11418, May 2002

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Laboratory report documenting GCMS analysis of sample AE11418 conducted on May 30, 2002.

NYC-WTC_000025386–000025402

Folder label: “GCMS X 5/16/02 A 5/20/02

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NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\1\DATA\052002\11418.D Vial: 8 Acq On : 20 May 2002 6:59 pm Operator: Mclean Sample : 5/16 eh Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\l\METHQDS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L

Peak Number 6 Phenanthrene-diO Concentration Rank 4 R.T. EstConc Area Relative to ISTD R.T.

23.11 0.41 ug/L 461879 Phenanthranene-dl0 22.95 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Phenanthrene-diO 188 C14D10 001517-22-2 86W 2 Anthracene-diO- 188 C14D10 001719-06-8 86— J 3 Pentacyclo[7.3.1.1.(4,12).0(2,7)... 188 C14H20 1000215-61-8 50 4 2-Quinolinecarboxaldehyde , 8-hyd. . . 188 C10H8N2O2 005603-22-5 40 Abundance Scan 3409 (23.109 min): 11418.D (-3402) (-) m/z 188.10 100.00% 188

5000 ,............ 80 94 22.80 23.00 23.20 23.40 42 52 66 158 i

z-> 0- r 1 ■11 --mm TP 11 4 H 1" '"I'11 n 1 II I’t 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 132 m/z 80.10 15.04%

Abundance #79827: Phenanthrene-d10 188

5000 22.80 23.00 23.20 23.40 80 94 m/ z 184.05 14.96% 160 30 42 52 66 108118 132 146 || 170179 0J' J....... H " " I" ’' I . ....... . . "Hl1"'I TTf I I i I [ i i i t j 1 i r i | t i t i । i i l i [ i t'l’l j'l i i i | r 1 r 1 | t’l l I | i i t i

/z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 Abundance #79826: Anthracene-d10- 188

22.80 23.00 23.20 23.40 5000 m/ Z 94.10 14.94%

80 94 160 , 17 30 42 52 66 , 108118 132 146 ,|| 170179 । 0-TWTPTTTTTTTTTHT 11111111111 — I [ ! I I I | I I I I | : J i I | I J J I | I I t i | I । I i | l I ‘ ‘ I I I [ i J i I tI’l" iiii m/z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 Abundance #79715: Pentacyclo[7.3.1.1 .(4,12).0(2,7).0(6,11 )]tetradeca... 1 ' i ■ ■ 188 22.80 23.00 23.20 23.40 m/z 189.10 11.52%

5000 79 91 55 67 105 131 100 117 m/z—> 0- i111' i ■1111 44 4 XXx — 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 22.80 23.00 23.20 23.40

11418.D 050102.M Thu May 23 10:46:11 2002 Page 9

NYC-WTC_000025399

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NYC-WTC_000025399Source: NYC Law Department, mirrored locally

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