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GCMS analysis results for sample AE11159, May 2002

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Laboratory report documenting GCMS analysis of sample AE11159 conducted on May 22, 2002, including surrogate recovery data.

NYC-WTC_000024681–000024691

Folder label: “GCMS X 5/13/02 A 5/15/02

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NYC 9/11 Public Portal Document Library Search Compound Report

Data File : C:\MSDCHEM\1\DATA\020515\11159.D Vial: 11 Acq On : 15 May 2002 9:42 pm Operator: Nefliu Sample : sample Inst Instrumen Mise Multiplr: 1.00 MS Integration Params: rteint.e Quant Method : C:\MSDCHEM\1\METHODS\SCAN020507.M (RTE Integrator) Title : Method 508 GC/MS Scan Library : C:\DATABASE\nist98.1 ********************************************************************* Peak Number 3 2-Propenal, 3-(3,4-dimethox... Concentration Rank 4 R.T. EstConc Area Relative to ISTD R.T. 31.09 0.29 ug/1 32684 Phenanthrene-dl0 31.72

1 Hit# of 5 Tentative ID MW MolForm CAS# Qual

l 2-Propenal, 3-(3,4-dimethoxyphen. . . 192 C11H12O3 004497-40-9 58 2 Phenanthrene, 9-methyl- 192 C15H12 000883-20-5 53 3 Phenanthrene, 2-methyl- 192 C15H12 002531-84-2 53 4 Bitoscanate 192 C8H4N2S2 004044-65-9 53 Abundance / Scan 4767 (31.088 min): 11159.D (-4757) (-) m/z 192.10 100.00% 192

5000

n/z-> AA 44 ,66 । 82 96 145 | TIWTTTITTTTTTTTTTITTT —mmmmmmmmmmmmmp 160

20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 + 30.80 31.00 31.20 31.40 m/z 191.00 17.35% Abundance #80953:2-Propenal, 3-(3,4-dimethoxyphenyl)- 1912 161

5000 L 30.80 31.00 31.20 31.40 77 91 121 149 177 m/ Z 160.20 13.89%

miz-> mm 52 64 - । 103 | 138 .... ................................ 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 . ...... ....... "11"

Abundance #81033: Phenanthrene, 9-methyl- 192 ‘ ‘ I 1 ' ' ' I ' 30.80 31.00 31.20 31.40 5000 m/z 193.00 12.58%

29 39 51 63 74 83 %6 115 126 139 152 165 176 | TITTTTETTTTTTTTTTWWTTTTTTTTTTTTITIWWTTTWTWWTTTTTTTHTTTTp-r n/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #125842: Phenanthrene, 2-methyl- 192 30.80 31.00 31.20 31.40 m/z 66.20 11.12% 5000

96 27 39 51 63 82 115 126 139 152 165 176 , 1—0————— IITT '■ ' i 1 1 1 1 i 1 1 i 1 1 1 1 i 1 1 m/z—> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 30.80 31.00 31.20 31.40

11159.D SCAN020507.M Thu May 16 09:54:42 2002 Page 5

NYC-WTC_000024689

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NYC-WTC_000024689Source: NYC Law Department, mirrored locally

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