GCMS sample preparation log, May 2002

NYC 9/11 Public Portal Document

Library Search Compound Report

Data File : C:\MSDCHEM\l\DATA\020515\0513LB2.D Vial: 4 Acq On : 15 May 2002 2:47 pm Operator: Nefliu Sample : 05/13 lab blk Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: rteint.e

Quant Method : C: \MSDCHEM\1\METHODS\SCAN020507 .M (RTE Integrator) Title : Method 508 GC/MS Scan Library : C:\DATABASE\nist98.1 ********************************************************************* Peak Number 4 Antipyrine Concentration Rank 2

R.T. EstConc Area Relative to' ISTD R.T.

31.96 0.30 ug/1 29982 Phenanthrene-dl0 31.72

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Antipyrine 188 C11H12N20 000060-80-0 50 2 Benzene, 1-(1-cyclohexen-l-yl)-4.. 188 C13H160 020758-60-5 50 3 Antipyrine 188 C11H12N2O 000060-80-0 50 4 Cyclohexanone, phenylhydrazone 188 C12H16N2 000946-82-7 50 Abundance Scan 4916 (31.964 min): 0513LB2.D (-4907) (-) m/z 188.15 100.00% 188

5000

| 82 94 49 66 I 128 156 190 170 । 258 31.60 31.80 32.00 32.20 ---------- m/z 189.10 18.38% m/z-> 20 40 60 80 100 120 140 160 180 200 220 240 260 Abundance #125690: Antipyrine 1(18

96 ............................................ 5000 77 56 31.60 31.80 32.00 32.20 m/z 66.00 15.54% 43 > i 159 173 -ll 4 , L1 11,115 129. nlz-> 20 40 60 (80 100 120 140 160 180 200 220 240 260 Abundance #79791: Benzene, 1-(1-cyclohexen-1-yl)-4-methoxy- 188 EdnuuuumuuIT 31.60 31.80 32.00 32.20 5000 160 m/z 94.40 15.22%

— 91 115 129 145 173 , ' H 4 I £5,444703.44,4. X 51 ■ ' i ■ 1 n/z-> 20 40 60 80 100 120 140 160 180 200 220 240 260 Abundance #125692: Antipyrine h—r T-r | i , . . I , r , , TT1 1(18 31.60 31.80 32.00 32.20 m/z 187.20 11.44% 96 5000 77 56

15,204.1 — — 1, .1 । 115 130 145 159 173 ' ■ i 1 1 1 ' i ' 1 1 1 I ' 1 1 1 1 1 1 m/z—> 20 40 ।60 180 100 120 140 160 180 200 220 240 260 31.60 31.80 32.00 32.20

0513LB2.D SCAN020507.M Thu May 16 14:44:14 2002 Page 6

NYC-WTC_000024435