GCMS calibration data for TCLP method, May 2002

NYC 9/11 Public Portal Document

Library Search Compound Report Data File C : \HPCHEM\ 1 \DATA\MAY03029568.D Vial: 42 Acq On 5 May 2002 8:11 am Operator: Sample GC/MS SCAN 4/23 FB Inst : 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS0501.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 1 2-Pentanone, 4-hydroxy-4-methy Concentration Rank 1 R.T. EstConc Area Relative to ISTD R.T. 8.16 13.27 ug/1 965994 1,4-Dichlorobenzene-d4 12.19 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 2-Pent .one, 4 - hydroxy - 4 - me t hyl - 116 C6H1202 000123-42-2 64 2 CH2=C !H2C(O)OCH3 100 C5H802 003724-55-8 9 3 Acet € 58 C3H60 000067-64-1 7 4 But e 58 C4H10 000106-97-8 5 Abundance Scan 340 (8.156 min): 9568.D (-) m/ z 43.05 100.00%| 43

5000 59 — 101 7.80 8.00 18.20 8.40 8.60

m/z-> ....................................... 38 I 10 20 30 40 +53+ 50 60 70 80 69 83 90 ■ ' 1 i ‘ 1 1 ' i ■ 100 110 m/ Z 59.10 42.46% Abundance #64274:2-Pentanone, 4-hydroxy-4-methyl- 43

5000 59 7 80 8.00 8 20 8.40 8.60 m/z 58.10 16.35% 27 101 -1.... 1,/........ +49 H 83 I I ■ ■ ■ ■ । 1 • । • i ■' • > । l ■ miz—> 10 20 30 40 50 60 70 80 90 100 110 Abundance #1448: CH2=CHCH2C(O)OCH3 43 - 7.80 8.00 8.20 8.40 8.60 5000 m/z 101.15 13.32%I

m/z-> Abundance

5000 .....................38 1 i ' 10 ' 1 ■ i ■ ' 20 ■ ■ i 30 ' ■ ■ 1 I1 40

43 ' ■ ■ t ■ ■ ■'' i ■ ■

50 58 60 #94: Acetone 70 ■ 72 ■ i । ■ i ■ ■ ■

80 ■ i ■ ■ ■

90 100 ■ I ■ ■ ■ ■ i ■

100 110

7 80 m/z 1 8.00 41.15 8.20 8.40 6.94% 8.60

15 58 27 ----- -------- m/z—> 10 20 30 40 50 60 70 80 90 100 110 7.80 8.00 8.20 8.40 8.60

9568.D GCMS0501.M Tue May 07 14:59:59 2002 Page 1

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