GCMS calibration data for TCLP method, May 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File C:\HPCHEM\l\DATA\MAY0302\9570.D Vial: 44 Acq On 5 May 2002 10:09 am Operator: Sample GC/MS SCAN 4/23 Inst : 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS0501.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 1 2-Pentanone, 4-hydroxy-4-methy Concentration Rank 1 R.T. EstConc Area Relative to ISTD R.T. 8.16 13.60 ug/1 989995 1,4-Dichlorobenzene-d4 12.19 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 2-Pentanone, 4-hydroxy-4-methyl- 116 C6H1202 000123-42-2 64 2 3 -Hydroxy-2 -pentanone 102 C5H10O2 003142-66-3 9 3 CH2=CHCM2C(O)OCH3 100 C5H802 003724-55-8 9 4 Acetone/ 58 C3H60 000067-64-1 7 Abundance Scan 340 (8.158 min): 9570.D (-) m/z 43.05 100.00% 43

5000 59

101 7 80 8.00 8.20 8.40 8.60 I ' ' ' ' I 1 1 ' ' I T 1fTr +53+ —Im—m 'J-...110 m/z ..................... 38 1 69 83 59.10 42.13% m/z-> 10 20 30 40 50 60 70 80 90 100 Abundance #64274:2-Pentanone, 4-hydroxy-4-methyl- 43

5000 _ / —__ 59 7.80 8.00 8.20 8.40 8.60 m/z 58.10 16.37%| 27 101 H +49 + I I 83 - i 1 1 1 1 r1 ■ ■' 1 i '' ■ ■ 1 i miz—> 10 20 30 40 50 60 70 80 90 100 110 Abundance #1691:3-Hydroxy-2-pentanone 31 5? ....... . /... .. ...... 7.80 8.00 8.20 8.40 8.60 5000 m/z 101.15 12.75%| 45 15 ...... I, ■ ■ i 1 ■ ■ 1 i ' ' ■ ' i' ■ 1 ' i ■ ■ ■ i ■ ■ . 66 73 I ■ ' ■ ' i ' ' ' i ‘ 84 ' i ' ■ ' 102 1 i ' ■ ‘ ' i ' mlz-> 10 20 30 40 50 60 70 80 90 100 110 Abundance #1448: CH2=CHCH2C(O)OCH3 43 7.80 8.00 8.20 8.40 8.60 I m/z 41.05 7.19% 5000

58 ....................38 I ' ■ ■ 1 i 1 ■ 1 1 i ■ 1 ■ 1 1 1 1* I 72 100 miz-> 10 20 30 40 50 60 70 80 90 100 110 7.80 8.00 8.20 8.40 8.60

9570.D GCMS0501.M Tue May 07 15:00:26 2002 Page 1

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