GCMS method parameters and calibration data, May 2002

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Data File : C:\MSDCHEM\1\DATA\020521\0517LB1.D Vial: 3 Acq On : 21 May 2002 10:15 am Operator: Nefliu Sample : 05/17 lab blk kb Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: rteint.e Quant Method : C:\MSDCHEM\1\METHODS\SCAN020521.M (RTE Integrator) Title : Method 508 GC/MS Scan Library : C:\DATABASE\nist98.1

Peak Number 3 Antipyrine Concentration Rank 3 R.T. EstConc Area Relative to ISTD R.T. 31.95 0.27 ug/1 26723 Phenanthrene-dl0 31.72 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Antipyrine 188 C11H12N2O 000060-80-0 53 2 Cyclohexanone, phenyl hydra zone 188 C12H16N2 000946-82-7 53 3 Anthracene-dlO- 188 C14D10 001719-06-8 37 4 Antipyrine 188 C11H12N2O 000060-80-0 36 Abundane Scan 4914 (31.952 min): 0517LB1.D (-4907) (-) m/z 188.10 100.00% 168

5000

44 61 80 94 160 31.60 31.80 32.00 32.20

niz-> m 10 20 30 40 50 60 70 80 90 100110 120 130 140 150 160 170 180 190 m/z 189.00 24.68% Abundance #125690: Antipyrine 188

96 /........................ 5000 77 56 31.60 31.80 32.00 32.20 105 m/z 187.30 18.34% 43 ,1 159 173.. 1 ... mz-> 0 --l 67 II H I 129 I 115 10 20 30 40 50 60 70 80 90 100110 120 130 140 150 160 170 180 190 ' I*1'11 ‘'

Abundance #79722: Cyclohexanone, phenylhydrazone 188 93 31.60 31.80 32.00 32.20 5000 m/z 184.15 16.41% 55 65 41 77 106 ". 41

miz-> 29 11. 0 TIT'I ! 1 Mr | „lll r il 1 , I1 npmtthnmttmtp i 159 170120 132 10 20 30 40 50 60 70 80 90 100110 120 130 140 150 160 170 180 190 U Abundance #79826: Anthracene-d10- 1(18 31.60 31.80 32.00 32.20 m/ z 44.00 10.29% 5000

80 94 150 । 17 30 42 52 ° J I 108 118 132 146 I 170179 1 0 mWWmWTTTTThmmmmm ' ' i 1 ■ ■ ■ i ■ ■ 1tit I ' 1 ' 1 I ' miz—> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 31.60 31.80 32.00 32.20

0517LB1.D SCAN020521.M Fri May 24 09:13:27 2002 Page 5

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