GCMS method parameters and calibration data, May 2002

NYC 9/11 Public Portal Document

Llbrary Search Compound Report

Data File : C:\MSDCHEM\1\DATA\02 0 521\0 517LB1.D Vial: 3 Acq On : 21 May 2002 10:15 am Operator: Nefliu Sample : 05/17 lab blk kb Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: rteint.e Quant Method : C:\MSDCHEM\1\METHODS\SCAN020521.M (RTE Integrator) Title : Method 508 GC/MS Scan Library : C:\DATABASE\nist98.1

Peak Number 2 2,4-Diamino-6-(hydroxymethy... Concentration Rank 2 R.T. EstConc Area Relative to ISTD R.T. 31.09 0.29 ug/1 28700 Phenanthrene-dl0 31.72 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 2,4- iamino-6-(hydroxymethyl)pte... 192 C7H8N60 000945-24-4 50 2 Anth acene, tetradecahydro-, (4a... 192 C14H24 001755-19-7 50 3 Anthracene, tetradecahydro- 192 C14H24 006596-35-6 50 4 Bitoscanate 192 C8H4N2S2 004044-65-9 50 Abundance Scan 4767 (31.088 min): 0517LB1 .D (-4758) (-) m/z 192.10 100.00% 192

5000 96 44 66 82 122 146 160 174 308 । 1 । 1 1 1 ' i —A—— A 30.80 31.00 31.20 31.40 Oh H ■ ■ ■ ! । H. ' i1 >>•»>» i i0111111111111/1111′1117 ‘ ‘ ‘ i ‘' l ..................... - i m/ z 96.10 28.08% nz-> 20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 Abundance #80958:2,4-Diamino-6-(hydroxymethyl)pteridine 163 19 2 43

5000 30.80 31.00 31.20 31.40 28 68 146 m/z 146.10 23.20%

mz-> 0 20 III 1, 40 92 106 121 + 17 TUT TI ‘ ‘'11 ''11 11 1' ' 11' '' 11 '1' I '' 60 80 100 120 140 160 180 200 220 240 260 280 300 Abundance #80932: Anthracene, tetradecahydro-, (4a.alpha.,8a.alpha.... 1 192 135 • rI * ' • ’ J ' ) ■ i • 1 1 ■ i ' ■ 30.80 31.00 31.20 31.40 67 m/ Z 82.00 18.63% 5000 81 95 121 150

z-> O-mPTTT 20 40 1 60 177 - ' i ■ ■ ■ ■ i ■ ■1111111111111111111' 80 100 120 140 160 180 200 220 240 260 280 300 Abundance #80931: Anthracene, tetradecahydro- ■ ■ i ' ■ ' ■ i ■ ■ i ■ 1 1 ' i 1 1 135 192 30.80 31.00 31.20 31.40 m/z 159.90 14.62% 5000 41 67 81 95 121 1 150

/z-> I, । I, | 0 TIT26$.444 20 40 60 164— ■ i ‘ ■ i ‘ 111111111111'11111' 80 100 120 140 160 180 200 220 240 260 280 300 30.80 31,00 31.20 31.40

0517LB1.D SCAN020521.M Fri May 24 09:13:27 2002 Page 4

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