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GCMS analysis log for sample AD30605, Jan 2002

Machine-extracted title · confidence 100%

Automated laboratory log recording GCMS analysis of sample AD30605 including detection of unknown compounds and surrogates.

NYC-WTC_000018194–000018213

Folder label: “GCMS X 12/27/01 A 1/16/02

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NYC 9/11 Public Portal Document Library Search Compound Report Data File C:\HPCHEM\1\DATA\DEC3101\30605.D Vial: 30 Acq On 1 Jan 2002 5:03 pm Operator: 209 GALOS Sample gems scan 12/19 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 3 Cyclotetrasiloxane, octamethyl Concentration Rank 4 R.T. EstConc Area Relative to ISTD R.T. 11.13 1.47 ug/1 376134 1,4-Dichlorobenzene-d4 11.67 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Cyclotetrasiloxane, octamethyl- 296 C8H2404Si4 000556-67-2 86 2 Benzene, 1-phenyl-4-(2-cyano-2-phen 281 C21H15N 027869-56-3 47 3 6,7-Benzo-phenothiazine-5, 5-dioxide 281 C16H11NO2S 000000-00-0 9 4 3,e-Bis^N-dimethylamino)-9-ethylcar 281 C18H23N3 057103-04-5 9 Abundance ” Scan 663 (11.133 mln): 30605.D(-) T"m/z 281.00 100.00% 201

5000 -

45 59 73 89 103 119 133 147 163 177 123 207 221 235 249 265 10.80 11.00 11.20 11.40 TTTmmuovipr r । r । ’r .i it . . ii* 1isi it • । q * . . । । n 4A1anaaadat i » . 1 Prr m/z 282.00 28.11% m/z-> 40 60 80 100 120 140 160 180 200 220 240 260 280 Abundance #41966: Cyclotetrasiloxane, octamethyl- 281

5000 10.80 11.00 11.20 11.40 ' ' ' m/z 283.00 17.62% 73 133 40 207 | 163 177 1?1 ! 235 249 265 ■ ■ i • ■ ■ ■ । ■ i ■ ■1 • । ■ ■ ■ ■ i ■ ■ • ■ ।■1' ।1111111111 "I rr> । 11 1 । । 11 । 1 r1 ■ mfz~> 40 60 80 100 120 140 160 180 200 220 240 260 280 Abundance #39543; Benzene, 1-phenyl-4-(2-cyano-2-phenylethenyi) 281 ‘ ■ i ■ ■ 1 ■ i ‘ • i ' 1 1 1 1 1 1 1 1 I 10.80 11.00 11.20 11.40 5000 m/z 192.90 11.68% 253 203 126 2 p 266 ri 224 240 ■1' । ■ 40 60 80 100 120 140 160 180 200 220 240 260 280 Abundance #39602: 6,7-Benzo-phenothiazine-5,5-dloxide ' 1 i ■ ■ • 1 i ■ 1 ■ * i ■ 1 ■ • i 281 10.80 11.00 11.20 11.40 rn/z 133.00 10.38% 5000 217 232 102 118 189 204 ' ‘ I * 1 ‘1 I‘k *• I * ‘ * I’ • ' • I ‘ ‘ ‘ * I 11‘* I’‘ ‘ I ‘ *111/252264 III 1 ■ i ■1 m/z-> 40 60 80 100 120 140 160 180 200 220 240 260 280 10.80 11.00 11J20 11.40

30605.D GCMS1126.M Wed Jan 23 08:28:38 2002 Page 3

NYC-WTC_000018203

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NYC-WTC_000018203Source: NYC Law Department, mirrored locally

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