GCMS analysis results for sample AD30425, Jan 2002

NYC 9/11 Public Portal Document

Library Search Compound Report

Data File : C:\HPCHEM\1\DATA\DEC2 701\30425.D Vial: 5 Acq On : 27 Dec 2001 3:04 pm Operator: 209 GALOS Sample : GC/MS SCAN 12/13 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 7 N-(Trifluoracetyl)-0,0',0"-tri Concentration Rank 5

R.T. EstConc Area Relative to ISTD R.T.

22.79 2.11 ug/1 888955 Phenanthrene-dl0 24.98

Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 N-(Trifluoracetyl)-0,0’,0"-tris(tri 495 C20H36F3NO4S13 000000-00-0 43 2 Benzeneethanamine, N-[(pentafluorop 563 C24H34F5NO3S13 055429-13-5 43 3 N-(Trifluoroacetyl)-N, 0,0’,0’’-tetr 553 C22H42F3NO4Si4 000000-00-0 35 4 Benzoic acid, 2,5-bis(trimethylsilo 370 C16H3004Si3 003618-20-0 28 Abundance Scan 1933 (22.788 mln): 30425.D (-) m/ z 73.0.0 100.00% 73

5000 147 355 ............. .......... 221 281 22.40 22.60 22.80 23.00 23.20 45 401 — 117.4 191, -.249, / I, | ,3?7 m/z 147.00 25.39% m/z-? 50 100 150 200 250 300 350 400 450 500 550 Abundance #58807: N-(Trifluoracetyl)-O,O',O"-tris(Wmethylsilyl)epin 73 355 5000 22.40 22.60 22.80 23.00 23.20 45 m/z 355.0. 24.92% | i, 140 184 281 480 ■ ''11 ■ ■ IrIapET i ■ ■ • ■ i ' ■ ■ ■ i ■ ■ ■ ■ i • ■ 1 ■ i ‘ ■ i ■ ' miz—> 50 100 150 200 250 300 350 400 450 500 550 Abundance #74706 Benzeneethanamine, N-tipentafluorophenyi)methyene] I 73 355 22.40 22.60 22.80 23.00 23.20 5000 m/z 221.05 17.88%

45 ’ I 208 • ‘ i ■ ■ ■ ‘ i ■ ■ ■ ' i ■ ■ ‘ ' i • ‘ 251 281 ■ I ■ ■ 1 ‘ I • ' .86 .. 458 ... 548 m/z-> 50 100 150 200 250 300 350 400 450 500 550 Abundance #60162: N-(Trifluoroacetyl)-N,O,O',O"-tetrakls(trimethylsi 73 22.40 22.60 22.80 23.00 23.20 m/z 281.00 14.59% 355 5000

45 — 147 193 267 538 **I***1***1**)ts ■ i ■ ■ ■ ■ i" ■ ‘ • i • ■ ■ • i ■ ■ • ■ i ‘ ■ i ■ ■ ■ i ■ ■ ■ ‘ i ■ • ■ ■ i1 1 1 ' i 1 1 1 1 I ' 1 miz-> 50 100 150 200 250 300 350 400 450 500 550 22.40 22.60 22.80 23.00 23.20

30425.D GCMS1126.M Wed Jan 02 11:04:09 2002 Page 7

NYC-WTC_000017716