GCMS calibration table for TCLP analysis, Nov 2001

NYC 9/11 Public Portal Document

Library Search Compound Report

Data File C:\HPCHEM\1\DATA\JAN0 802\28327.D Vial: 5 Acq On 8 Jan 2002 4:16 pm Operator: 209 GALOS Sample 508 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS0103.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 8 N-(Trifluoracetyl)-0,0',0"-tri Concentration Rank 3

R.T. EstConc Area Relative to ISTD R.T.

22.64 5.26 ug/1 2929170 Phenanthrene-dl0 24.81

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 N-(Trifluoracetyl)-0,0',0"-tris(tri 495 C20H36F3NO4Si3 000000-00-0 35 2 Benzeneethanamine, N-[ (pentafluorop 563 C24H34F5NO3Si3 055429-13-5 25 3 N- (Tri fluorcface tyl) -N, O, O’ , 0 '•-tetr 553 C22H42F3NO4Si4 000000-00-0 22 4 3-Isopropojfey-l, 1,1,7,7,7-hexamethyl 576 C18H5207Si7 071579-69-6 20 Abundance Scan 1916 (22.637 min): 28327.D (-) m/z 73.0,0 100.00% 73

5000 147 355 __ —.......... - 221 281 i Wz~> 0- 1 45 50 ‘TI r * 191, 117 100 191 — 150 200 249, 1327 250 _ 300 350 400 a 450 500 550 22.40 22.60 22.80 23.00 rn/z 147.00 27.07% Abundance #58807: N-(Trifluoracetyl)-O,0‘,0"-tris(trimethylsilyl)epin 7b 355

5000- TTIIT 1 1 i1 1 1 1 i 1 1 22.40 22.60 22.80 23.00 45 m/z 355.05 25.51% I L 140 184 281 480 TTTTITTT 1 1 i ■ । i । [ ■ । । . । । । । । । । miz-> 50 100 150 200 250 300 350 400 450 500 550 Abundance #74706: tenzeneethanamine, N-K(pentafluorophenyl)methylene] 73 355 i — TP 1 1 f । PPP TP 22.40 22.60 22.80 23.00 5000 m/z 221.05 19.31%

! 45 208 251 281 LMz~> —50 100 150 200 250 300 TT TTTT T 350 386 400 458 450 500 548 550 Abundance #60162: N-(Trifluoroacetyl)-N,0,0,0"-tetrakis(trimethylsi -r-r-j-r-T ' 1 I 1 ' 1 ' I ‘ ' 73 _____ 22.40 22.60 22.80 23.00 m/z 281.00 14.24% 355 5000

45 147 193 ! lf 267 538 —........ — ......... — ' ' I ‘ " 'I. TTTrT TT n pi-. . । ii r ("[■! TT I । i i i D TT I j i ' ! I | I I miz-> 50 100 150 200 250 300 350 400 450 500 550 22.40 22.60 22.80 23.00

28327.D GCMS1126.M Wed Jan 09 09:15:16 2002 Page 8

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