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GCMS analysis results for sample AD29523, Jan 2002

Machine-extracted title · confidence 100%

GCMS analysis report for sample AD29523 listing unknown compounds and surrogate recovery data from January 28, 2002.

NYC-WTC_000036798–000036814

Folder label: “GCMS X 12/7/01 A 1/2/02

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NYC 9/11 Public Portal Document

Library Search Compound Report

Data File : C:\HPCHEM\l\DATA\DEC2701\29523.D Vial: 37 Acq On : 29 Dec 2001 12 :10 am Operator: 209 GALOS Sample : GC/MS SCAN 12/7 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 7 N-(Trifluoroacetyl)-0,O',0'1-t Concentration Rank 5

R.T. EstConc Area Relative to ISTD R.T.

22.79 0.96 ug/1 607357 Phenanthrene-dl0 24.99

Hit# Of 5 Tentative 1 MW MolForm CAS# Qual

I N- (Trif luoroacety1)-0, O ' , O ' ' - tris (t 481 C19H34F3NO4Si3 000000-00-0 37 2 Benzeneethanamine, N- [ (pentafluorop 563 C24H34F5NO3Si3 055429-13-5 37 3 N-(Trifluorace tyl) -0,0',O"-tris(tri 495 C20H36F3NO4Si3 000000-00-0 37 4 3-1sopropoxy—l ,1,1,7,7,7-hexamethyl 576 C18H5207Si7 071579-69-6 37 'Abundance « Scan 1933 (22.787 min): 29523.D (-) m/ z 73.00 100.00% 73

5000- 147 OOI 355 221 281 I 22.40 22.60 22.80 23.00 23.20 : 45 327 1 401 — —IPT 191, [ 251 I 117 | m/z 147.00 24.65% m/z-> 50 100 150 200 250 300 350 400 450 500 550 'Abundance #58326: N-(Trifluoroacetyl)-O,O',O"-tris(trimethylsilyl)no 73 355 5000- ■ i • ■ TTT—mmm 22.40 22.60 22.80 23.00 23.20 45 m/z 3 55.0. 23.26% ■ ■ i * ■ 1 120 147 193 265 481 mlz—> 50 100 150 200 250 300 350 400 450 500 550 'Abundance #74706: Benzeneethanamine, N-K(pentafluorophenyl)methylene] 73 355

22.40 22.60 22.80 23.00 23.20 5000 m/z 221.0 16.54%

45 208 251 281 ; 386 458 548 ■ ■ i ■ ■ ■ ■ i ■

miz-> 50 100 150 200 250 300 350 400 450 500 550 Abundance #58807: N-(Trifluoracetyl)-O,O',O"-tris(trimethylsilyl)epin 73 22.40 22.60 22.80 23.00 23.20 355 m/z 281.00 13.46% 5000

m/z-> , L — —nnn 45

50 100 140 150 184 200 250 281 300 350 400 450 480 500 550 ------ ' i ' ' ' ' i ' ' 22.40 22.60 22.80 23.00 23.20

29523.D GCMS1126.M Tue Jan 08 12:09:51 2002 Page 7

NYC-WTC_000036811

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NYC-WTC_000036811Source: NYC Law Department, mirrored locally

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