GCMS reference analysis results, Jan-Feb 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

Data File C: \HPCHEM\ 1 \DATA\JANO 802 \REFC. D Vial: 5 Acq On 9 Jan 2002 5:39 pm Operator: 209 GALOS Sample gems scan 12/24 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: Feb 6 10:55 2002 Quant Results File: GCMS0103.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0103.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Thu Dec 13 14:40:46 2001 Response via : Initial Calibration DataAcq Meth : GCMS0103

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 11.53 152 798186 20.00 ug/1 0.00 10) Naphthalene-d8 15.12 136 3133513 20.00 ug/1 0.00 17) Acenaphthene-diO 20.39 164 1561935 20.00 ug/1 0.00 29) Phenanthrene-diO 24.81 188 2234449 20.00 ug/1 0.00 38) Chrysene-dl2 32.84 240 1382761 20.00 ug/1 0.00 44) Perylene-dl2 36.91 264 797789 20.00 ug/1 0.01

System Monitoring Compounds 37) 2,4-DDD 29.89 235 99470 3.88 ug/mL -0.18 Spiked Amount 5.000 Recovery = 77.60%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 5.30 74 50572 1.32 ug/1 93 3) bis(2-Chloroethyl)ether 10.96 93 120801 1.95 ug/1 98 4) 1,3-Dichlorobenzene 11.43 146 69108 1.25 ug/1 100 5) 1,4-Dichlorobenzene 11.58 146 77748m 1.40 ug/1 6) 1,2-Dichlorobenzene 12.08 146 78497 1.53 ug/1 99 7) 2,2’-oxybi s(1-Chioropropan 12.43 45 201322 2.19 ug/1 97 8) N-Nitroso-di-n-propylamine 12.82 70 84666 2.19 ug/1 97 9) Hexachloroethane 12.92 117 21759 0.96 ug/1 99 11) Nitrobenzene 13.21 77 110353 1.82 ug/1 97 12) 1sophorone 13.85 82 241285 2.24 ug/1 99 13) bis(2-Chloroethoxy)methane 14.54 93 148132 2.12 ug/1 99 14) 1,2,4-Trichlorobenzene 15.02 180 60577 1.42 ug/1 98 15) Naphthalene 15.18 128 279676 1.95 ug/1 99 16) Hexachlorobutadiene 15.74 225 20065 0.93 ug/1 98 18) Hexachlorocyclopentadiene 0.00 237 0 N.D. 19) 2-Chloronaphthalene 18.66 162 146615 1.81 ug/1 98 20) Dimethylphthalate 19.78 163 229773 2.42 ug/1 99 21) 2,6-Dinitrotoluene 19.99 165 34461 1.53 ug/1 88 22) Acenaphthylene 19.92 152 237982 2.00 ug/1 100 2 3) Acenaphthene 20.48 153 176482 2.16 ug/1 98 24) 2,4-Dinitrotoluene 21.16 165 42285 1.47 ug/1 90 25) Diethylphthalate 21.91 149 245349 2.61 ug/1 99 26) 4-Chlorophenyl-phenylether 22.03 204 82876 2.17 ug/1 99 27) Fluorene 22.00 166 189797 2.29 ug/1 99 28) Azobenzen/ 1,2-Diphenylhyd 22.50 77 217320 1.95 ug/L 98

(#) = qualifier out of range (m) = manual integration REFC.D GCMS0103.M Wed Feb 06 10:57:18 2002 Page 1

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