GCMS reference analysis, sample AD31432, Jan 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

Data File : C:\HPCHEM\1\DATA\JAN1802\REF.D Vial: 5 Acq On : 18 Jan 2002 7:33 pm Operator: 209 GALOS Sample : gc/ms scan 12/31 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: Feb 6 14:40 2002 Quant Results File: GCMS0103.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0103.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Thu Dec 13 14:40:46 2001 Response via : Initial Calibration DataAcq Meth : GCMS0103

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 11.50 152 748431 20.00 ug/1 -0.03 10) Naphthalene-d8 15.09 136 2894254 20.00 ug/1 -0.03 17) Acenaphthene-diO 20.36 164 1456990 20.00 ug/1 -0.03 29) Phenanthrene-diO 24.77 188 2007891 20.00 ug/1 -0.04 38) Chrysene-dl2 32.80 240 1201712 20.00 ug/1 -0.04 44) Perylene-dl2 36.87 264 741997 20.00 ug/1 -0.03

System Monitoring Compounds 37) 2,4-DDD 29.85 235 107572 4.67 ug/mL -0.22 Spiked Amount 5.000 Recovery = 93.40%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 5.29 74 48630 1.35 ug/1 87 3) bis(2-Chloroethyl)ether 10.93 93 121652 2.10 ug/1 95 4) 1,3-Dichlorobenzene 11.40 146 74059 1.43 ug/1 96 5) 1,4-Dichlorobenzene 11.55 146 83129 1.59 ug/1 # 95 6) 1,2-Dichlorobenzene 12.05 146 84967 1.76 ug/1 97 7) 2,2'-oxybis(1-Chloropropan 12.40 45 211100 2.45 ug/1 96 8) N-Nitroso-di-n-propylamine 12.79 70 86555 2.39 ug/1 98 9) Hexachloroethane 12.89 117 23353 1.09 ug/1 95 11) Nitrobenzene 13.18 77 119500 2.14 ug/1 100 12) 1sophorone 13.82 82 234393 2.35 ug/1 99 13) bis(2-Chloroethoxy)methane 14.51 93 144962 2.25 ug/1 99 14) 1,2,4-Trichlorobenzene 14.99 180 69694 1.77 ug/1 98 15) Naphthalene 15.15 128 298883 2.26 ug/1 99 16) Hexachlorobutadiene 15.70 225 20601 1.03 ug/1 98 18) Hexachiorocyclopentadiene 0.00 237 0 N.D. 19) 2-Chloronaphthalene 18.63 162 156663 2.08 ug/1 99 20) Dimethylphthalate 19.75 163 215298 2.43 ug/1 100 21) 2,6-Dinitrotoluene 19.96 165 33308 1.59 ug/1 # 87 2 2) Acenaphthylene 19.88 152 248253 2.23 ug/1 99 23) Acenaphthene 20.44 153 181579 2.38 ug/1 99 24) 2,4-Dinitrotoluene 21.12 165 39779 1.48 ug/1 # 87 25) Diethylphthalate 21.88 149 224305 2.56 ug/1 98 26) 4-Chlorophenyl-phenylether 22.00 204 83709 2.35 ug/1 99 27) Fluorene 21.96 166 186221 2.41 ug/1 99 2 8) Azobenzen/ 1,2-Diphenylhyd 22.46 77 213929 2.06 ug/L 98

(#) = qualifier out of range (m) = manual integration REF.D GCMS0103.M Wed Feb 06 15:05:31 2002 Page 1

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