GCMS calibration quantitation report, June 2002

NYC 9/11 Public Portal Document Quantitation Report (QT Reviewed)

Data File : C:\MSDCHEM\l\DATA\061102\REFl.D Vial: 5 Acq On : 11 Jun 2002 1:08 pm Operator: Sample : gc/ms scan 6/11 Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: EVENTS.E Quant Time: Jun 11 15:49:42 2002 <Quant Results File: 060302.RES Quant Method : C:\MSDCHEM\1\METHODS\060302.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Last Update : Tue Jun 11 15:43:45 2002 Response via : Initial Calibration DataAcq Meth : 508SCAN

Internal Standards R.T. Qlon Response Cone Units Dev(Min) 1) 1,4-dichlorobenzene-d4 9.90 152 5853711 40.00 ug/L 0.00 10) Napthalene-d8 13.39 136 23740872 40.00 ug/L 0.00 17) Acenapthalene-dlO 18.53 164 13007019 40.00 ug/L 0.00 29) Phenanthranene-dlO 22.91 188 19493116 40.00 ug/L 0.00 37) Chrysene-dl2 30.76 240 12339519 40.00 ug/L 0.00 43) Perylene-dl2 34.66 264 6608677 40.00 ug/L 0.00 System Monitoring Compounds 27) TCMX 20.50 209 2561618 32.75 ug/L 0.00 Spiked Amount 40.000 Recovery 81.88% Target Compounds Qvalue 2) n-nitros-dimethyl amine 3.84 74 852184m 7.74 ug/L 3) bis(2-Chloroethyl)ether 9.31 93 3036489 14.14 ug/L 99 4) 1,3-Dichlorobenzene 9.72 146 2613442 12.27 ug/L 96 5) 1,4-Dichlorobenzene 9.94 146 2751177 11.90 ug/L 99 6) 1,2-Dichlorobenzene 10.32 146 2713292 13.28 ug/1 99 7) 2,2'oxybis(1-Chloropropane 10.74 45 4922628m 14.46 ug/L 8) N-nitroso-di-propylamine 11.10 70 2207440 14.64 ug/L 95 9) Hexachloroethane 11.22 117 782319 8.91 ug/L 96 11) Nitrobenzene 11.45 77 2948369 13.22 ug/L 99 12) Isophorone 12.17 82 6489361 16.15 ug/L 99 13) bis(2-Chloroethoxy) methan 12.90 93 3836843 14.39 ug/L 99 14) 1,2,4-Trichlorobenzene 13.26 180 2261505 13.02 ug/L 99 15) Napthalene 13.45 128 9404907 15.49 ug/L 99 16) Hexachlorobutadiene 13.89 225 779265 9.51 ug/L 97 18) 2-Chloronaphthalene 16.89 162 5420126 16.63 ug/L 99 .19) Dimethylphthalate 17.97 163 6397239 15.50 ug/L 99 20) 2,6-Dinitrotoluene 18.08 165 1037263 15.94 ug/L 93 21) Acenapthylene 18.08 152 8363747 15.05 ug/L 99 22) Acenapthalene 18.62 153 5637075 16.24 ug/L 99 23) 2,4-Dinitrotoluene 19.23 165 1416397 17.41 ug/L 95 24) Diethylphthalate 20.10 149 6388805 17.74 ug/L 98 25) 4-Chlorophenyl-phenylether 20.29 204 3060517 15.42 ug/L 100 26) Fluorene 20.16 166 6766128 16.68 ug/L 100 2 8) Azobenzene 20.74 77 7006823 14.86 ug/L 99 30) Nnitrosodiphenylamine 20.65 169 3978417 17.79 ug/L 100 31) 4-Bromophenyl-phenylether 21.72 248 1544715 16.06 ug/L 98 32) Hexachlorobenzene 21.75 284 1530100 16.62 ug/L 97 3 3) Phenanthrene 22.97 178 9460604 16.90 ug/L 100 34) Anthracene 23.12 178 9118058 15.89 ug/L 99 35) Di-n-butylphthalate 25.05 149 9497894 13.77 ug/L 100 (#) = qualifier out of range (m) = manual integration REFl.D 060302.M Tue Jun 11 15:51:23 2002 Page 1

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