GCMS reference analysis results for volatile organics, June 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

Data File C:\MSDCHEM\1\DATA\0 6 0 7 0 2\REF1.D Vial: 9 Acq On 7 Jun 2002 3:06 pm Operator: Sample gc/ms scan 6/3 Inst : Instrumen Miso Multiplr: 1.00 MS Integration Params: EVENTS.E Quant Time: Jun 10 11:12:27 2002 Quant Results File: 060302.RES Quant Method : C:\MSDCHEM\1\METHODS\060302.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Last Update : Thu Jun 06 15:03:45 2002 Response via : Initial Calibration DataAcq Meth : 508SCAN

Internal Standards R.T. Qlon Response Cone Units Dev(Min) 1) 1,4-dichlorobenzene-d4 9.89 152 4889718 40.00 ug/L 0.00 10) Napthalene-d8 13.39 136 19670406 40.00 ug/L 0.00 17) Acenapthalene-dlO 18.53 164 10928699 40.00 ug/L 0.00 29) Phenanthranene-dlO 22.91 188 16893268 40.00 ug/L 0.00 37) Chrysene-dl2 30.76 240 11002031 40.00 ug/L 0.00 43) Perylene-dl2 34.65 264 6071590 40.00 ug/L 0.00

System Monitoring Compounds 27) TCMX 20.50 209 2216823 28.27 ug/L 0.00 Spiked Amount 40.000 Recovery 70.67% Target Compounds Qvalue 2) n-nitros-dimethyl amine 3.88 74 779505m 8.48 ug/L 3) bis(2-Chloroethyl)ether 9.31 93 2392741 13.34 ug/L 98 4) 1,3-Dichlorobenzene 9.72 146 2192285 12.32 ug/L 100 5) 1,4-Dichlorobenzene 9.94 146 2318061 12.00 ug/L 99 6) 1,2-Dichlorobenzene 10.31 146 2251468 13.20 ug/1 99 7) 2,2‘oxybis(1-Chloropropane 10.76 • 45 3954124m 13.91 ug/L 8) N-nitroso-di-propylamine 11.09 70 1716821 13.63 ug/L 98 9) Hexachloroethane 11.22 117 643825 8.78 ug/L 97 11) Nitrobenzene 11.45 77 2218361 12.01 ug/L 99 12) Isophorone 12.16 82 5125279 15.40 ug/L 99 13) bis(2-Chloroethoxy) methan 12.90 93 3040409 13.76 ug/L 98 14) 1,2,4-Trichlorobenzene 13.26 180 1905577 13.24 ug/L 100 15) Napthalene 13.45 128 7608529 15.13 ug/L 100 16) Hexachlorobutadiene 13.89 225 684555 10.08 ug/L 99 18) 2-Chloronaphthalene 16.89 162 4534585 16.82 ug/L 97 19) Dimethylphthalate 17.96 163 5295268 15.30 ug/L 100 20) 2,6-Dinitrotoluene 18.07 165 779396 14.29 ug/L 95 21) Acenapthylene 18.08 152 6886544 15.10 ug/L 98 22) Acenapthalene 18.61 153 4640387 16.28 ug/L 99 23) 2,4-Dinitrotoluene 19.23 165 1037755 15.83 ug/L 94 24) Diethylphthalate 20.10 149 5314709 17.76 ug/L 99 25) 4-Chlorophenyl-phenylether 20.29 204 2597952 15.86 ug/L 98 26) Fluorene 20.15 166 5636209 16.90 ug/L 100 28) Azobenzene 20.73 77 5641685 14.39 ug/L 98 30) Nnitrosodiphenylamine 20.65 169 3457119 17.84 ug/L 99 31) 4-Bromophenyl-phenylether 21.71 248 1335377 16.02 ug/L 99 32) Hexachlorobenzene 21.75 284 1359796 17.05 ug/L 98 3 3) Phenanthrene 22.97 178 8079478 16.65 ug/L 99 34) Anthracene 23.12 178 7852644 15.79 ug/L 99 35) Di-n-butylphthalate 25.05 149 8234964 13.78 ug/L 100 (#) = qualifier out of range (m) = manual integration REFl.D 060302.M Mon Jun 10 11:14:16 2002 Page 1

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