GCMS calibration quantitation report, June 2002

NYC 9/11 Public Portal Document Quantitation Report (QT Reviewed)

Data File : C:\MSDCHEM\1\DATA\061102\REF2.D Vial: 6 Acq On : 11 Jun 2002 1:57 pm Operator: Sample : gc/ms scan 6/11 Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: EVENTS.E Quant Time: Jun 11 15:46:46 2002 <Quant Results File: Q60302.RES Quant Method : C:\MSDCHEM\1\METHODS\060302.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Last Update : Tue Jun 11 15:43:45 2002 Response via : Initial Calibration DataAcq Meth : 508SCAN

Internal Standards R.T. Qlon Response Cone Units Dev(Min) 1) 1,4-dichlorobenzene-d4 9.90 152 5585302 40.00 ug/L 0.00 10) Napthalene-d8 13.39 136 22388809 40.00 ug/L 0.00 17) Acenapthalene-dlO 18.53 164 12224412 40.00 ug/L 0.00 2 9) Phenanthranene-dl0 22.91 188 18720797 40.00 ug/L 0.00 37) Chrysene-dl2 30.77 240 13238051 40.00 ug/L 0.00 43) Perylene-dl2 34.66 264 7016559 40.00 ug/L 0.00 System Monitoring Compounds 27) TCMX 20.50 209 2395926 32.60 ug/L 0.00 Spiked Amount 40.000 Recovery 81.50% Target Compounds Qvalue 2) n-nitros-dimethyl amine 3.85 74 729282m 6.95 ug/L 3) bis(2-Chloroethyl)ether 9.31 93 2791279 13.63 ug/L 98 4) 1,3-Dichlorobenzene 9.72 146 2369367 11.66 ug/L 99 5) 1,4-Dichlorobenzene 9.94 146 2534512 11.49 ug/L 99 6) 1,2-Dichlorobenzene 10.31 146 2480812 12.73 ug/1 98 7) 2,2'oxybis(1-Chloropropane 10.74 45 4460378m 13.73 ug/L 8) N-nitroso-di-propylamine 11.09 70 2031170 14.11 ug/L 98 9) Hexachloroethane 11.22 117 707748 8.45 ug/L 98 11) Nitrobenzene 11.45 77 2683225 12.76 ug/L 98 12) Isophorone 12.16 82 5977374 15.78 ug/L 100 13) bis(2-Chloroethoxy) methan 12.90 93 3507628 13.94 ug/L 99 14) 1,2,4-Trichlorobenzene 13.26 180 2060629 12.58 ug/L 99 15) Napthalene 13.45 128 8648352 15.11 ug/L 99 16) Hexachlorobutadiene 13.89 225 718316 9.30 ug/L 97 18) 2-Chloronaphthalene 16.89 162 4955298 16.18 ug/L 98 19) Dimethylphthalate 17.96 163 5887565 15.18 ug/L 100 20) 2,6-Dinitrotoluene 18.08 165 957186 15.70 ug/L 97 21) Acenapthylene 18.08 152 7717461 14.77 ug/L 97 22) Acenapthalene 18.62 153 5128007 15.72 ug/L 98 23) 2,4-Dinitrotoluene 19.23 165 1279097 16.94 ug/L 95 24) Diethylphthalate 20.10 149 5871719 17.35 ug/L 97 25) 4-Chlorophenyl-phenylether 20.29 204 2800451 15.01 ug/L 98 26) Fluorene 20.16 166 6182275 16.22 ug/L 99 28) Azobenzene 20.74 77 6431791 14.51 ug/L 99 30) Nnitrosodiphenylamine 20.65 169 3588370 16.71 ug/L 99 31) 4-Bromophenyl-phenylether 21.72 248 1430355 15.48 ug/L 96 32) Hexachlorobenzene 21.75 284 1412113 15.97 ug/L 97 3 3) Phenanthrene 22.97 178 8749553 16.27 ug/L 99 34) Anthracene 23.12 178 8556823 15.52 ug/L 99 35) Di-n-butylphthalate 25.05 149 9073856 13.68 ug/L 99 (#) = qualifier out of range (m) = manual integration REF2.D 060302.M Tue Jun 11 15:48:53 2002 Page 1

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