GCMS calibration table for method 508SCAN, April 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

Data File C:\MSDCHEM\1\DATA\02 0417\04 0 8REF2.D Vial: 6 Acq On 17 Apr 2002 1:31 pm Operator: Nefliu Sample 04/08 ref Inst Instrumen Mise Multiplr: 1.00 MS Integration Params: EVENTS.E Quant Time: Apr 18 09:09:53 2002 Quant Results File: 041702SCAN. RE

Quant Method C:\MSDCHEM\1\METHODS\041702SCAN.M (Chemstation Integrator) Title 508 Modified GC/MS scan Last Update Wed Apr 17 08:01:11 2002 Response via Initial Calibration DataAcq Meth 508SCAN

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 9.99 152 6949016 40.00 ug/L -0.02 10) Napthalene-d8 13.49 136 27044147 40.00 ug/L -0.03 17) Acenapthalene-dlO 18.63 164 14698140 40.00 ug/L -0.02 29) Phenanthranene-dlO 23.02 188 22459491 40.00 ug/L -0.02 37) Chrysene-dl2 30.89 240 16213904 40.00 ug/L -0.04 43) Perylene-dl2 34.79 264 11576346 40.00 ug/L -0.02

System Monitoring Compounds 2 7) TCMX 20.60 207 500988 6.15 ug/L 0.00 Spiked Amount 8.000 Recovery 76.88%

Target Compounds Qvalue 2) n-nitros-dimethyl amine 3.90 74 1120907 8.70 ug/L 90 3) bis(2-Chloroethyl)ether 9.40 93 3987299 17.34 ug/L 89 4) 1,3-Dichlorobenzene 9.82 146 2136160 8.37 ug/L 98 5) 1,4-Dichlorobenzene 10.03 146 2411275 9.30 ug/L 99 6) 1,2-Dichlorobenzene 10.41 146 2601759 10.61 ug/1 99 7) 2,2'oxybis(1-Chloropropane 10.86 45 6011494m 17.32 ug/L 8) N-nitroso-di-propylamine 11.19 70 2915727 18.24 ug/L 92 9) Hexachloroethane 11.31 117 318108 3.49 ug/L 91 11) Nitrobenzene 11.54 77 3873771 15.39 ug/L 93 12) Isophorone 12.26 82 6408571 14.30 ug/L 96 13) bis(2-Chloroethoxy) methan 13.00 93 4938353 17.41 ug/L 97 14) 1,2,4-Trichlorobenzene 13.35 180 1853584 9.80 ug/L 98 15) Napthalene 13.54 128 10190401 15.04 ug/L 99 16) Hexachlorobutadiene 13.99 225 184439 1.87 ug/L 96 18) 2-Chloronaphthalene 16.99 162 5490235 14.33 ug/L 97 19) Dimethylphthalate 18.07 163 8838116 21.65 ug/L 99 20) 2,6-Dinitrotoluene 18.18 165 1541874 16.98 ug/L 98 21) Acenapthylene 18.19 152 9995934 17.90 ug/L 98 22) Acenapthalene 18.72 153 6562469 16.31 ug/L 97 23) 2,4-Dinitrotoluene 19.34 165 1992950 17.49 ug/L 90 24) Diethylphthalate 20.21 149 8988902 21.44 ug/L 99 25) 4-Chlorophenyl-phenylether 20.39 204 3277158 16.78 ug/L 97 26) Fluorene 20.26 166 7978906 17.85 ug/L 98 28) Azobenzene 20.85 77 8470684 17.13 ug/L # 90 30) Nnitrosodiphenylamine 20.76 169 4391188 15.35 ug/L 94 31) 4-Bromophenyl-phenylether 21.83 248 1691518 14.10 ug/L 97 32) Hexachlorobenzene 21.86 284 1803742 14.05 ug/L 97 33) Phenanthrene 23.09 178 11818141 18.81 ug/L 98 34) Anthracene 23.24 178 10717419 17.44 ug/L 97 35) Di-n-butylphthalate 25.16 149 14725486 20.90 ug/L 100

(#) = qualifier out of range (m) = manual integration 0408REF2.D 04 1702SCAN.M Thu Apr 18 09:10:39 2002 Page 1

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