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GCMS analysis results for unknown compounds, June 2002

Machine-extracted title · confidence 90%

Laboratory report documenting GCMS analysis of sample AE12737 with surrogate recovery data and identification of unknown compounds.

NYC-WTC_000015253–000015281

Folder label: “GCMS X 6/3/02 A 6/7/02

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NYC 9/11 Public Portal Document Library searen compound Report Data File C:\MSDCHEM\l\DATA\060702\12738.D Vial: 14 Acq On 7 Jun 2002 7:10 pm Operator: Sample Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\060302.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 20 Dibutyl phthalate Concentration Rank 13 R.T. EstConc Area Relative to ISTD R.T. 25.05 0.86 ug/L 771231 Phenanthranene-dl0 22.90 Hit# of 5 Tentative ID MW MolForm CAS# Qu 1 Dibutyl phthalate 278 C16H2204 000084-74-2 86 2 Dibutyl phthalate 278 C16H2204 000084-74-2 78 3 1,2-Benzenedicarboxylic acid, bi... 278 C16H2204 000084-69-5 78 4 Dibutyl phthalate 278 C16H2204 000084-74-2 78 Abundance Scan 3739 (25.048 min): 12738.D (-3726) (-) m/z 149.00 100.00% 149

5000

0! ' ' I ' 3157 73 87104 121. . 1 ... _..... 205 223 m/z 24.80 25.00 25.20 25.40 41.10 13.90% miz-> 20 40 60 80 100 120 140 160 180 200 220 240 260 280 Abundance #123485: Dibutyl phthalate 149

5000 A-I 44-4-A4 24.80 25.00 25.20 25.40 rn/z 150.00 10.16% 01 . 41 56 76 91 104 121 135 | 167 186 205 223 278 n/z-> 20 40 60 80 100 120 140 160 180 200 220 240 260 280 Abundance #123493: Dibutyl phthalate 149 ............ ... ............... 24.80 25.00 25.20 25.40 5000 m/z 57.10 8.84%

14 28 41 57 . 76 91 105 121135 01 . UT 1 n r r 1’111111112101***—m0_—T—TDT’T 168182 295 223 278 niz-> 20 40 60 80 100 120 140 160 180 200 220 240 260 280 Abundance #66775:1,2-Benzenedicarboxylic acid, bis(2-methylpropyl)... 149 .. MM... 24.80 25.00 25.20 25.40 m/z 43.10 7.68% ). 5000

29 57 223

n/z-> 0 ,.47.43.4, +.76,91.794 121.135., 167 189 205 | 236 263 278 — 20 40 60 80 100 120 140 160 180 200 220 240 260 280 24.80 25.00 25.20 25.40

12738.D 060302.M Mon Jun 10 11:45:49 2002 Page 23

NYC-WTC_000015280

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NYC-WTC_000015280Source: NYC Law Department, mirrored locally

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