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GCMS analysis results for unknown compounds, June 2002

Machine-extracted title · confidence 90%

Laboratory report documenting GCMS analysis of sample AE12737 with surrogate recovery data and identification of unknown compounds.

NYC-WTC_000015253–000015281

Folder label: “GCMS X 6/3/02 A 6/7/02

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NYC 9/11 Public Portal Document Llbrary Search Compound Report

Data File C:\MSDCHEM\1\DATA\060702\12738.D Vial: 14 Acq On 7 Jun 2002 7:10 pm Operator: Sample Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.e

Quant Method : C:\MSDCHEM\1\METHODS\060302.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L

Peak Number 19 Anthracene-dlO- Concentration Rank 16 R.T. EstConc Area Relative to ISTD R.T. 23.06 0.34 ug/L 300569 Phenanthranene-dl0 22.90 Hit# Of 5 Tentative ID MW MolForm CAS# Qual

1 Anthracene-dlO- 2 Phenanthrene-diO 3 Pentacyclo[7.3.1.1. (4,12) .0(2,7) ... 188 C14D10 188 C14D10 188 C14H20 001719-06-8 87 001517-22-2 74 1000215-61-8 59 J 4 Pentacyclo[8.4.0.0(3,7) .0 (4,14) .... 188 C14H20 1000099-27-2 36 Abundance Scan 3401 (23.062 min): 12738.D (-3395) (-) m/z 188.10 100.00% 188

5000

80 94 160 40 52 66 22.80 23.00 23.20 23.40 0— 1 * " 11 -HTTT I— 1 ■ i11" i ■ ■ ‘ ■ i ■' ■ ■ i ■ • • ■ i •' ■ ■ i ■ ■ ... III......... . I’T m/z 189.10 19.87% mfe-> 10 20 30 40 50 60 70 80 90 100110 120 130 140 150 160 170 180 190 Abundance #79826: Anthracene-d10- 188

5000 22.80 23.00 23.20 23.40 m/z 184.10 15.58% 66 80 94 160 0- 17 30 42 52 “ * r *' * r1 * ■ i1 ‘4 * H11 ++l108,118..132.14641701794—— n/z-> 10 20 30 40 50 60 70 80 90 100110 120 130 140 150 160 170 180 190 Abundance #79827: Phenanthrene-d10 1(0 ..............................................

22.80 23.00 23.20 23.40 5000 m/z 80.10 14.50%

80 94 160 30 42 52 66 , 11 108118 132 146 ,i,l 170179,1 0 '■ I" ■ ■ l1 ■ ■ ■ I" " I" " 111" I 111" I l |' TTTm n/z-> 10 20 30 40 50 60 70 80 90 100110 120 130 140 150 160 170 180 190 Abundance #79715: Pentacyclo[7.3.1.1.(4,12).0(2,7).0(6,11)]tetradeca... - 1(0 22.80 23.00 23.20 23.40 m/z 94.05 12.21% 5000 79 91 55 67 105 131 100 117 i 145 159 173 I 0-mmmpnp Tife-> 10 20 30 40 50 60 70 80 90 100110 120 130 140 150 160 170 180 190 22.80 23.00 23.20 23.40

12738.D 060302.M Mon Jun 10 11:45:49 2002 Page 22

NYC-WTC_000015279

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NYC-WTC_000015279Source: NYC Law Department, mirrored locally

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