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GCMS analysis results for unknown compounds, sample AE10204, May 2002

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Laboratory report showing gas chromatography-mass spectrometry results for unidentified organic compounds in sample AE10204 on May 10, 2002.

NYC-WTC_000044994–000045009

Folder label: “GCMS X 4/30/02 A 5/8/02

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NYC 9/11 Public Portal Document Library Search Compound Report Data File C:\MSDCHEM\1\DATA\050802\10204 .D Vial: 22 Acq On 9 May 2002 8:31 am Operator: Mclean Sample 4/30 eh Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e

Quant Method : C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L Peak Number 6 Anthracene-dlO- Concentration Rank 2 R.T. EstConc Area Relative to ISTD R.T. 23.11 0.44 ug/L 476217 Phenanthranene-dl0 22.95

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Anthracene-dlO- 188 C14D10 001719-06-8 933 2 Phenanthrene-dlO 188 C14D10 001517-22-2 87/ 3 Pentacyclo[7.3.1.1. (4,12) . 0 (2,7) . . . 188 C14H20 1000215-61-8 50 4 2-Quinolinecarboxaldehyde,8-hyd... 188 C10H8N202 005603-22-5 40 Abundance Scan 3409 (23.109 min): 10204.D (-3403) (-) m/z 188.10 100.00% 108

5000

I I | I I I ! | I-1 | I-J 1 1 i 1 1

57 66 80 J4 156 i 22.80 23.00 23.20 23.40

m/z-> 0- r 1 r' i 10 20 30 40 50 60 70 43 + | l f !\ | ! I I ! ! ! I l ( r > : I | | I ! I | I ! I I | । ! > I | । I I I | ! I I ■ | I ! ! > | I ! | l | ! > ! I | ! I ! < | I l r l

80 90 100 110 120 130 140 150 160 170 180 190 L ‘T‘n m/z 189.10 15.74% Abundance #79826: Anthracene-d10- 188

— 5000 22.80 23.00 23.20 23.40 m/ z 94.10 14.07% 80 94 160 , i 66 17 30 42 52 108 118 132 1 0 TT————dm1—1011—03101hm 11111111111 iiii) । T’l 11111111111 > 11 ] 111 > 11 146,.................. m/z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 Abundance #79827: Phenanthrene-d10 188 ........ /......................... 1ti I ' I II 11 I I 1 1 1 1 [ 1 >1'1 22.80 23.00 23.20 23.40 5000 m/ z 80.10 12.50%

80 94 160 30 42 52 66 J 108 118 132 146 .il 170179,1 0 I | I T I' i | i i i > | < i i r | I ■ ■ < | I I i । | I I I i | I H I I I I I | I I i i 11 | i r j i m [ i i i i | I i I 11-1 i t-i । i IIHl’t i i i । i i t i | mr /z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 Abundance #79715: Pentacyclo[7.3.1.1 (4,12).0(2,7).0(6,11)]tetradeca... 188 y 22.80 23.00 23.20 23.40 ' I 1 1 1 ' I ' ' ' ' I

m/z 184.10 10.77%

5000 79 91 55 67 10 117 131 105 145 159 173 m/z-> 0 I1 1 11 I ll— — — 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 - I I I I I I I < I I I I I > I I I I 1 I I I > I JU ' • I ' ' 1 1 I 1 1 '■ I 1 1 1 1 I 22.80 23.00 23.20 23.40

10204.D 050102.M Thu May 09 13:38:28 2002 Page 9

NYC-WTC_000045007

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