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GCMS analysis results, sample AE09968, May 2002

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Gas chromatography-mass spectrometry analysis report for sample AE09968, detecting unknown compounds and 2,4-DDD surrogate with 78% recovery, dated May 9, 2002.

NYC-WTC_000043938–000043957

Folder label: “GCMS X 4/25/02 A 5/7/02

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NYC 9/11 Public Portal Document

Library Search Compound Report

Data File C:\MSDCHEM\1\DATA\050602\9968.D Vial : 25 Acq On 7 May 2002 7:14 am Operator: Mclean Sample 4/25 Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e

Quant Method : C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L

Peak Number 7 Anthracene-dlO- Concentration Rank 2

R.T. EstConc Area Relative to ISTD R.T. 23.11 0.59 ug/L 607735 Phenanthranene-dl0 22.96 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Anthracene-dlO- 188 C14D10 001719-06-8 81 2 Phenanthrene-diO 188 C14D10 001517-22-2 74 3 Pentacyclo[7.3.1.1. (4,12) . 0 (2,7) . . . 188 C14H20 1000215-61-8 38 4 2-Quinolinecarboxaldehyde , 8-hyd... 188 C10H8N2O2 005603-22-5 28 Abundance Scan 3409 (23.109 min): 9968.D (-3402) (-) m/z 188.10 ' 100.00% 188

5000

80 94 158 । 22.80 23.00 23.20 23.40 42 52 66 ......... 132 । ri । i i i i । i । i I7‘m I I i *i ] rtrgi । |1 । i*i । | I । । । r 1" i TTTTT i "III1....... qrt;.... m/ z 94.10 20.76% m/z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 Abundance #79826: Anthracene-d 10- 188

5000 22.80 23.00 23.20 23.40 m/z 189.20 17.24% KK 80 94 160 , . 17 30 42 52 00 I J 108 118 132 ————————— TT146—44179179— . m/z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 Abundance #79827: Phenanthrene-d10 188 .......... /.............................. 22.80 23.00 23.20 23.40 5000 m/z 80.00 16.16%

80 94 160 30 42 52 I | I r i I | I I r I | I i i i | I i i ( | I I |i 66 I I 1 । f i rI | i I | | 11 108 118 132 146 170179,1,1 | I I । । | I f । I । । i । । | । I । । | I । 1 i i' r i IT [■ i t‘1‘1 |*ri ti [ i ! i i ttri" i ri + m/z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 Abundance #79715: Pentacyclo[7.3.1.1 .(4,12).0(2,7).0(6,11)]tetradeca... I _'_l > I l 1111 I ! I I > I I I I I I I 188 22.80 23.00 23.20 23.40 m/z 184.10 14.58%

5000 79 91 55 67 131

/z—> ................ I,I , I I I I I I I I I I I I 1 I I I I I I I I I I I I I

10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 105 117 1145159/173.. 1 +44-444— । । i i । 1 । । ' I ' | 1 1 1 1] r |"i । । i | i ri I 1 | I — । । i n । | I I i i |—i—i—i—i—r

22.80 23.00 23.20 23.40

9968.D 050102.M Tue May 07 15:47:03 2002 Page 11

NYC-WTC_000043953

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