GCMS calibration data, DEP Labs, May 2002

NYC 9/11 Public Portal Document Quantitation Report (QT Reviewed)

Data File : C:\HPCHEM\l\DATA\MAY3002\REF2.D Vial: 10 Acq On : 30 May 2002 10:56 pm Operator: Morgan Sample : gc/ms scan 5/29 Inst : 209 Mise Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: May 31 11:21 2002 Quant Results File:„GCMS0520.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0520.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Mon May 20 15:10:30 2002 Response via : Initial Calibration DataAcq Meth : GCMS0528

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.07 152 584364 40.00 ug/1 -0.08 10) Naphthalene-d8 15.69 136 2341246 40.00 ug/1 -0.10 17) Acenaphthene-diO 20.99 164 1108743 40.00 ug/1 -0.10 30) Phenanthrene-diO 25.43 188 1720072 40.00 ug/1 -0.10 38) Chrysene-dl2 33.48 240 1065102 40.00 ug/1 -0.13 44) Perylene-dl2 37.66 264 672478 40.00 ug/1 -0.14 System Monitoring Compounds 28) TCMX 23.13 209 195074 35.01 ug/L -0.10 Spiked Amount 40.000 Recovery 87.52%

Target Compounds Qvalue 2) N-nitrosodimethylamine 5.72 74 139391 7.95 ug/1 80 3) bis(2-Chloroethyl)ether 11.47 93 275875 11.87 ug/1 94 4) 1,3-Dichlorobenzene 11.97 146 253674 13.49 ug/1 98 5) 1,4-Dichlorobenzene 12.11 146 263044 12.77 ug/1 97 6) 1,2-Dichlorobenzene 12.63 146 258692 14.49 ug/1 100 7) 2,2'-oxybis(1-Chloropropan 12.95 45 463150 8.81 ug/1 # 94 8) N-Nitrosodi-n-propylamine 13.33 70 201022 12.18 ug/1 # 86 9) Hexachloroethane 13.47 117 83282 9.47 ug/1 97 11) Nitrobenzene 13.75 77 261569 12.85 ug/1 # 85 12) 1sophorone 14.39 82 575838 14.29 ug/1 95 13) bis(2-Chloroethoxy)methane 15.08 93 332075 12.29 ug/1 99 14) 1,2,4-Trichlorobenzene 15.58 180 212791 14.55 ug/1 99 15) Naphthalene 15.75 128 831609 15.73 ug/1 # 81 16) Hexachlorobutadiene 16.30 225 76374 10.79 ug/1 97 18) Hexachlorocyclopentadiene 18.49 237 23216 5.16 ug/1 98 19) 2-Chloronaphthalene 19.26 162 428365 17.33 ug/1 96 20) Dimethylphthalate 20.35 163 514597 16.54 ug/1 99 21) 2,6-Dinitrotoluene 20.56 165 106050 16.38 ug/1 93 2 2) Acenaphthylene 20.52 152 668400 14.76 ug/1 98 2 3) Acenaphthene 21.08 153 453283 16.75 ug/1 99 24) 2,4-Dinitrotoluene 21.73 165 130174 18.34 ug/1 89 25) Diethylphthalate 22.48 149 522382 18.17 ug/1 99 26) 4-Chlorophenylphenylether 22.62 204 235838 16.41 ug/1 97 2 7) Fluorene 22.61 166 492393 17.95 ug/1 98 29) Azobenzene 23.09 77 537265 12.98 ug/L # 90 31) N-Nitrosodiphenylamine 23.02 168 175630 15.49 ug/1 # 87 32) 4-Bromophenylphenylether 24.09 248 117151 13.05 ug/1 95 33) Hexachlorobenzene 24.53 284 138744 14.40 ug/1 94 34) Phenanthrene 25.49 178 705074 17.00 ug/1 99 (#) = qualifier out of range (m) = manual integration REF2.D GCMS0520.M Fri May 31 11:22:34 2002 Page 1

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