GCMS calibration report, DEP Box 15, May 2002

NYC 9/11 Public Portal Document Quantitation Report (QT Reviewed) 9 Data File : C:\HPCHEM\1\DATA\MAY2902\REF1.D Vial: 4 Acq On : 29 May 2002 2:17 pm Operator: Morgan Sample : gc/ms scan 5/23 Inst : 209 Mise Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: May 30 8:16 2002 Quant Results File:GCMS0528.RES Quant Method : C:\HPCHEM\1\METHODS\GCMS0528.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Tue May 28 08:55:48 2002 Response via : Initial Calibration DataAcq Meth : GCMS0528

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.07 152 595791 40.00 ug/1 -0.08 10) Naphthalene-d8 15.69 136 2389097 40.00 ug/1 -0.10 17) Acenaphthene-diO 21.00 164 1145047 40.00 ug/1 -0.09 30) Phenanthrene-diO 25.43 188 1794230m 40.00 ug/1 -0.10 38) Chrysene-dl2 33.47 240 1076934m 40.00 ug/1 -0.13 44) Perylene-dl2 37.65 264 693036 40.00 ug/1 -0.15

System Monitoring Compounds 28) TCMX 23.14 209 243565 30.81 ug/L -0.10 Spiked Amount 40.000 Recovery 77.03% Target Compounds Qvalue 2) N-nitrosodimethylamine 5.73 74 173334 9.69 ug/1 82 3) bis(2-Chloroethyl)ether 11.47 93 354905 14.98 ug/1 94 4) 1,3-Dichlorobenzene 11.96 146 312308 16.29 ug/1 100 5) 1,4-Dichlorobenzene 12.11 146 330706 15.74 ug/1 96 6) 1,2-Dichlorobenzene 12.63 146 324137 17.81 ug/1 98 7) 2,2'-oxybis(1-Chloropropan 12.96 45 587632 10.96 ug/1 # 91 8) N-Nitrosodi-n-propylamine 13.34 70 243044 14.45 ug/1 +i 85 9) Hexachloroethane 13.47 117 103020 11.49 ug/1 92 11) Nitrobenzene 13.75 77 326898 15.74 ug/1 # 88 12) Isophorone 14.40 82 687553 16.72 ug/1 # 94 13) bis(2-Chloroethoxy)methane 15.08 93 421405 15.29 ug/1 # 97 14) 1,2,4-Trichlorobenzene 15.58 180 263727 17.67 ug/1 99 15) Naphthalene 15.76 128 1039761 19.28 ug/1 # 81 16) Hexachlorobutadiene 16.30 225 93602 12.96 ug/1 98 18) Hexachiorocyclopentadiene 18.49 237 11362 2.45 ug/1 100 19) 2-Chloronaphthalene 19.25 162 536654 21.03 ug/1 96 20) Dimethylphthalate 20.35 163 625568 19.47 ug/1 99 21) 2,6-Dinitrotoluene 20.56 165 118720 17.75 ug/1 # 96 2 2) Acenaphthylene 20.52 152 813345 17.39 ug/1 98 23) Acenaphthene 21.09 153 559101 20.01 ug/1 99 24) 2,4-Dinitrotoluene 21.73 165 147473 20.12 ug/1 # 82 25) Diethylphthalate 22.48 149 640147 21.57 ug/1 99 26) 4-Chlorophenylphenylether 22.63 204 287472 19.37 ug/1 99 27) Fluorene 22.60 166 605129 21.36 ug/1 99 29) Azobenzene 23.09 77 641267 15.00 ug/L 92 31) N-Nitrosodiphenylamine 23.02 168 170911m 14.46 ug/1 32) 4-Bromophenylphenylether 24.09 248 144540 15.43 ug/1 3 3) Hexachlorobenzene 24.52 284 170402 16.96 ug/1 34) Phenanthrene 25.50 178 858036m 19.83 ug/1 (#) = qualifier out of range (m) = manual integration REFl.D GCMS0528.M Thu May 30 08:16:55 2002 Page 1

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