GCMS calibration data, DEP Labs, May 2002

NYC 9/11 Public Portal Document Quantitation Report (QT Reviewed)

Data File : C:\HPCHEM\1\DATA\MAY3002\REF1.D Vial: 9 Acq On : 30 May 2002 9:56 pm Operator: Morgan Sample : gc/ms scan 5/29 Inst : 209 Mise Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: May 31 11:08 2002 Quant Results File:„GCMS0520.RES *** Quant Method : C:\HPCHEM\1\METHODS\GCMS0520.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Mon May 20 15:10:30 2002 Response via : Initial Calibration DataAcq Meth : GCMS0528

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.07 152 603634 40.00 ug/1 -0.08 10) Naphthalene-d8 15.70 136 2430880 40.00 ug/1 -0.10 17) Acenaphthene-diO 20.99 164 1143284 40.00 ug/1 -0.10 3 0) Phenanthrene-dl0 25.43 188 1791956 40.00 ug/1 -0.11 38) Chrysene-dl2 33.48 240 1112828 40.00 ug/1 -0.13 44) Perylene-dl2 37.65 264 706729 40.00 ug/1 -0.15 System Monitoring Compounds 28) TCMX 23.13 209 202507 35.24 ug/L -0.10 Spiked Amount 40.000 Recovery 88.10% Target Compounds Qvalue 2) N-nitrosodimethylamine 5.73 74 138859 7.66 ug/1 79 3) bis(2-Chloroethyl)ether 11.47 93 283079 11.79 ug/1 92 4) 1,3-Dichlorobenzene 11.97 146 248278 12.78 ug/1 99 5) 1,4-Dichlorobenzene 12.11 146 260163 12.22 ug/1 99 6) 1,2-Dichlorobenzene 12.63 146 255865 13.88 ug/1 99 7) 2,2'-oxybis(1-Chloropropan 12.95 45 475146 8.75 ug/1 # 94 8) N-Nitrosodi-n-propylamine 13.34 70 204212 11.98 ug/1 # 85 9) Hexachioroethane 13.47 117 81622 8.98 ug/1 98 11) Nitrobenzene 13.75 77 264651 12.53 ug/1 # 86 12) 1sophorone 14.39 82 573896 13.72 ug/1 95 13) bis(2-Chloroethoxy)methane 15.08 93 345580 12.32 ug/1 98 14) 1,2,4-Trichlorobenzene 15.59 180 215755 14.21 ug/1 98 15) Naphthalene 15.75 128 846726 15.43 ug/1 # 81 16) Hexachlorobutadiene 16.30 225 74901 10.19 ug/1 95 18) Hexachlorocyclopentadiene 18.50 237 24477 5.28 ug/1 98 19) 2-Chloronaphthalene 19.25 162 447156 17.55 ug/1 96 20) Dimethylphthalate 20.35 163 531728 16.58 ug/1 100 21) 2,6-Dinitrotoluene 20.56 165 109621 16.42 ug/1 94 2 2) Acenaphthylene 20.52 152 696310 14.91 ug/1 98 2 3) Acenaphthene 21.08 153 470377 16.86 ug/1 98 24) 2,4-Dinitrotoluene 21.73 165 138865 18.97 ug/1 # 86 25) Diethylphthalate 22.48 149 548216 18.50 ug/1 100 26) 4-Chlorophenylphenylether 22.63 204 246226 16.62 ug/1 96 27) Fluorene 22.61 166 509345 18.01 ug/1 100 29) Azobenzene 23.09 77 559386 13.10 ug/L # 90 31) N-Nitrosodiphenylamine 23.02 168 193239 16.36 ug/1 # 85 32) 4-Bromophenylphenylether 24.10 248 123360 13.19 ug/1 97 33) Hexachlorobenzene 24.53 284 143758 14.32 ug/1 97 3 4) Phenanthrene 25.49 178 731524 16.93 ug/1 99 (#) = qualifier out of range (m) = manual integration REFl.D GCMS0520.M Fri May 31 11:09:50 2002 Page 1

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