GCMS reference data sample AE12152, May 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed) Data File : C:\HPCHEM\1\DATA\MAY2402\REF1.D Vial: 4 Acq On : 24 May 2002 6:29 pm Operator: Morgan Sample : gc/ms scan 5/22 Inst : 209 Mise : Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: May 28 11:42 2002 <Quant Results File: GCMS0520 .RES *e- Quant Method : C:\HPCHEM\1\METHODS\GCMS0520.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Tue May 28 11:39:13 2002 Response via : Initial Calibration DataAcq Meth : GCMS0520

Internal Standards R.T. Qlon Response Cone Units Dev(Min) 1) 1,4-Dichlorobenzene-d4 12.14 152 591266 40.00 ug/1 0.00 10) Naphthalene-d8 15.78 136 2384777 40.00 ug/1 -0.02 17) Acenaphthene-diO 21.09 164 1162399 40.00 ug/1 0.00 30) Phenanthrene-diO 25.53 188 1700586 40.00 ug/1 0.00 38) Chrysene-dl2 33.60 240 938566 40.00 ug/1 0.00 44) Perylene-dl2 37.83 264 651890 40.00 ug/1 0.02

System Monitoring Compounds 28) TCMX 23.24 209 197650 33.83 ug/L 0.00 Spiked Amount 40.000 Recovery 84.58% Target Compounds Qvalue 2) N-nitrosodimethylamine 5.80 74 151090 8.51 ug/1 80 3) bis(2-Chloroethyl)ether 11.54 93 306860 13.05 ug/1 91 4) 1,3-Dichlorobenzene 12.04 146 267228 14.05 ug/1 97 5) 1,4-Dichlorobenzene 12.19 146 282161 13.53 ug/1 98 6) 1,2-Dichlorobenzene 12.70 146 274695 15.21 ug/1 100 7) 2,2'-oxybi s(1-Chioropropan 13.02 45 497742 9.36 ug/1 # 93 8) N-Nitrosodi-n-propylamine 13.41 70 211604 12.67 ug/1 # 86 9) Hexachloroethane 13.55 117 84317 9.47 ug/1 93 11) Nitrobenzene 13.82 77 271218 13.09 ug/1 # 85 12) Isophorone 14.47 82 586820 14.30 ug/1 # 94 13) bis(2-Chloroethoxy)methane 15.16 93 361023 13.12 ug/1 # 98 14) 1,2,4-Trichiorobenzene 15.67 180 232960 15.64 ug/1 99 15) Naphthalene 15.83 128 902353 16.76 ug/1 98 16) HexaChlorobutadiene 16.38 225 70799 9.82 ug/1 97 18) Hexachlorocyclopentadiene 18.58 237 19131 4.06 ug/1 97 19) 2-Chloronaphthalene 19.34 162 469761 18.13 ug/1 97 20) Dimethylphthalate 20.44 163 537864 16.49 ug/1 100 21) 2,6-Dinitrotoluene 20.65 165 108367 15.96 ug/1 93 22) Acenaphthylene 20.61 152 707946 14.91 ug/1 98 2 3) Acenaphthene 21.18 153 479069 16.89 ug/1 99 24) 2,4-Dinitrotoluene 21.83 165 129258 17.37 ug/1 # 82 25) Diethylphthalate 22.58 149 537354 17.83 ug/1 99 26) 4-Chlorophenylphenylether 22.73 204 238001 15.80 ug/1 97 2 7) Fluorene 22.70 166 522031 18.15 ug/1 98 29) Azobenzene 23.19 77 536632 12.36 ug/L # 89 31) N-Nitrosodiphenylamine 23.12 168 186758 16.67 ug/1 # 85 32) 4-Bromophenylphenylether 24.19 248 115942 13.06 ug/1 95 33) Hexachlorobenzene 24.63 284 138072 14.50 ug/1 # 91 3 4) Phenanthrene 25.60 178 715421 17.44 ug/1 99 (#) = qualifier out of range (m) = manual integration REFl.D GCMS0520.M Tue May 28 11:42:23 2002 Page 1

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