GCMS calibration report, DEP Box 15, May 2002

NYC 9/11 Public Portal Document Quantitation Report (QT Reviewed)

Data File : C:\HPCHEM\1\DATA\MAY2902\REF2 .D Vial: 5 Acq On : 29 May 2002 3:16 pm Operator: Morgan Sample : gc/ms scan 5/23 Inst : 209 Mise Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: May 30 8:17 2002 Quant Results File:„GCMS0528.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0528.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Tue May 28 08:55:48 2002 Response via : Initial Calibration DataAcq Meth : GCMS0528

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.07 152 520781 40.00 ug/1 -0.08 10) Naphthalene-d8 15.69 136 2096677 40.00 ug/1 -0.10 17) Acenaphthene-diO 20.99 164 993568 40.00 ug/1 -0.10 30) Phenanthrene-diO 25.42 188 1542260 40.00 ug/1 -0.11 38) Chrysene-dl2 33.47 240 951422 40.00 ug/1 -0.13 44) Perylene-dl2 37.65 264 614665 40.00 ug/1 -0.15 System Monitoring Compounds 28) TCMX 23.14 209 211923 30.90 ug/L -0.10 Spiked Amount 40.000 Recovery 77.25% Target Compounds Qvalue 2) N-nitrosodimethylamine 5.73 74 155353 9.94 ug/1 80 3) bis(2-Chloroethyl)ether 11.47 93 307849 14.87 ug/1 94 4) 1,3-Dichlorobenzene 11.96 146 288129 17.19 ug/1 99 5) 1,4-Dichlorobenzene 12.11 146 299563 16.31 ug/1 97 6) 1,2-Dichlorobenzene 12.63 146 287936 18.10 ug/1 99 7) 2,2'-oxybis(1-Chloropropan 12.96 45 509597 10.88 ug/1 # 93 8) N-Nitrosodi-n-propylamine 13.34 70 209866 14.27 ug/1 +i 85 9) Hexachloroethane 13.47 117 94107 12.00 ug/1 94 11) Nitrobenzene 13.75 77 279695 15.35 ug/1 89 12) 1sophorone 14.40 82 592616 16.42 ug/1 # 93 13) bis(2-Chloroethoxy)methane 15.08 93 360571 14.91 ug/1 97 14) 1,2,4-Trichlorobenzene 15.58 180 233904 17.86 ug/1 99 15) Naphthalene 15.76 128 896789 18.94 ug/1 # 81 16) Hexachlorobutadiene 16.30 225 88148 13.91 ug/1 100 18) Hexachlorocyclopentadiene 18.49 237 9134 2.27 ug/1 96 19) 2-Chloronaphthalene 19.25 162 463353 20.92 ug/1 95 20) Dimethylphthalate 20.35 163 533447 19.14 ug/1 98 21) 2,6-Dinitrotoluene 20.56 165 100695 17.35 ug/1 91 22) Acenaphthylene 20.52 152 678713 16.73 ug/1 98 23) Acenaphthene 21.08 153 473265 19.52 ug/1 99 24) 2,4-Dinitrotoluene 21.72 165 120113 18.88 ug/1 # 88 25) Diethylphthalate 22.48 149 537787 20.88 ug/1 98 26) 4-Chiorophenylphenylether 22.63 204 249740 19.40 ug/1 99 2 7) Fluorene 22.60 166 515032 20.95 ug/1 100 29) Azobenzene 23.09 77 546303 14.72 ug/L # 91 31) N-Nitrosodiphenylamine 23.02 168 119191 11.73 ug/1 # 85 32) 4-Bromophenylphenylether 24.09 248 123096 15.29 ug/1 93 3 3) Hexachlorobenzene 24.52 284 145946 16.90 ug/1 100 34) Phenanthrene 25.50 178 724439 19.48 ug/1 100 (#) = qualifier out of range (m) = manual integration REF2.D GCMS0528.M Thu May 30 08:19:05 2002 Page 1

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