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GCMS calibration table for TCLP extraction method

Machine-extracted title · confidence 90%

GCMS analysis results for sample AE11603 dated June 4, 2002, documenting unknown compounds and surrogate recovery.

NYC-WTC_000013968–000013996

Folder label: “GCMS X 5/24/02 A 5/28/02

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NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\l\DATA\052802\11603.D Vial: 9 Acq On : 28 May 2002 8:49 pm Operator: McLean Sample : 5/24 ad re-ext Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 17 Phenanthrene, 9-methyl- Concentration Rank 18 R.T. EstConc Area Relative to ISTD R.T. 22.54 0.26 ug/L 285119 Phenanthranene-dl0 22.91 Hit# of 5 Tentative ID MW MolForm CAS# Qual l Phenanthrene, 9-methyl- 192 C15H12 000883-20-5 59 2 Phenant hrene, 2-methyl- 192 C15H12 002531-84-2 50 3 Phenanthrene, l-methyl- 192 C15H12 000832-69-9 59 4 Anthracene, 2-methyl- 192 C15H12 000613-12-7 53 Abundance Scan 3312 (22.539 min): 11603.D (-3305) (-) m/z 192.00 100.00% 192

5000 / 1 146 90 96 160 22.20 22.40 22.60 22.80 44 52 66 8 ,l nfe-> 118 0 . ।।11 > 11 >-| 111111H111 > 111 h 11111111 m । mHpp 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 mm m/z 191.10 26.00% Abundance #81033: Phenanthrene, 9-methyl- 192

5000 22.20 22.40 22.60 22.80 m/z 146.00 19.32% 29 39 51 63 74 83 * 115 126 139 152 165 176 ... 0- (.... ।. >1... . |. (-rt-.. ।. I'lu I’I "fl i I'l 111 .. 11 rr. 111111 (. rTl ti . 11'11111111 111 rl'i । 11 niz-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #125842: Phenanthrene, 2-methyl- 1912 1 22.20 22.40 22.60 22.80 5000 m/z 193.10 14.15%

mz-> Abundance 27 39 51 63 0 JWOT—pHmpDTTp 96 82 l , 115 126 139 152 195 176 , 20 30 40 50 60 70 80 90 100 110120130 140 150 160 170 180 190 200 #125856: Phenanthrene, 1-methyl- u 1 ' i ■ • ‘ ■ i ■ ■ i ■ ■ ■ ■ i ■ "f 1912 22.20 22.40 22.60 22.80 m/z 96.00 12.63% 5000

96 IRA 82 l 115 126 139 152 120 178 0 27 —00139—0— 51 TT 00Bn63 — ‘t-rrp-r ■ ■ i ’ ■ 1 ■ i ■ ‘ i • ■ ■ ■ i ‘ TOI n/z-> 2030405060 70 8090 100 110 120 130 140 150 160 170 180 190 200 22.20 22.40 22.60 22.80

11603.D 052202.M Thu May 30 10:38:55 2002 Page 20

NYC-WTC_000013992

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NYC-WTC_000013992Source: NYC Law Department, mirrored locally

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