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GCMS calibration table for TCLP extraction method

Machine-extracted title · confidence 90%

GCMS analysis results for sample AE11603 dated June 4, 2002, documenting unknown compounds and surrogate recovery.

NYC-WTC_000013968–000013996

Folder label: “GCMS X 5/24/02 A 5/28/02

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NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\l\DATA\052802\11603.D Vial: 9 Acq On : 28 May 2002 8:49 pm Operator: McLean Sample : 5/24 ad re-ext Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L

Peak Number 18 Anthracene-dlO- Concentration Rank 16

R.T. EstConc Area Relative to ISTD R.T. 23.06 0.28 ug/L 310555 Phenanthranene-dl0 22.91

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Anthracene-dlO- 188 C14D10 001719-06-8 91 ] 2 Phenanthrene-diO 188 C14D10 001517-22-2 87^ 3 2-Quinolinecarboxaldehyde, 8-hyd... 188 C10H8N2O2 005603-22-5 40 4 3-Amino-4-methyl-6-methoxyquinoline 188 C11H12N2O 1000213-71-3 40 Abundance Scan 3401 (23.062 min): 11603.D (-3395) (-) m/z 188.15 100.00% 188

5000

80 94 160 22.80 23.00 23.20 23.40

miz-> 0 mmntmpH -HH 44 alula 66 10 2030405060 70 8090 100110120130140150160170180190 132 ■ ■ i ■"11" ■' i1" • i ■ ■ m/z 94.00 17.49% Abundance #79826: Anthracene-d10- 188

5000 ) 1 22.80 23.00 23.20 23.40 m/z 189.20 17.27% 80 94 160 , , 17 30 42 52 66 1 108118 132 146 +.179179,..., 0 'I"1'I"" I" TTTTH M 1111 h > 11 n t j n h pi ii |H ! 11 n i m mfz-> 10 20 30 40 50 60 70 80 90 100110 120 130 140 150 160 170 180 190 Abundance #79827: Phenanthrene-d10 188 .............................................. 22.80 23.00 23.20 23.40 5000 rn/z 80.10 16.60%

80 94 160 , 30 42 52 66 11 108 118 132 146 ,|,| 170179,1,1 0- ——01—3—30——“TTHtuor miz-> 10 2030405060 70 8090 100110120130140150160170180190 Abundance #125696:2-Quinolinecarboxaldehyde, 8-hydroxy-, oxime , . । Ar j m , 'i । । । । . । i > 188 22.80 23.00 23.20 23.40 m/z 184.10 10.73%

5000 143

+ 89 115 170 51 64 76 I 102 |. 130 158 15 0^1 | ■ I > I | I I I I | 1 1 1 1 | > i ■ ■ ■ ■ I' ■ ■ ■ i ■ “ m/z—> 10 20 30 40 50 60 70 80 90 100110120130140150160170180190 22.80 23.00 23.20 23.40

11603.D 052202.M Thu May 30 10:38:56 2002 Page 21

NYC-WTC_000013993

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NYC-WTC_000013993Source: NYC Law Department, mirrored locally

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