GCMS reference analysis results for organic contaminants, March 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

Data File : C:\HPCHEM\l\DATA\MAR1902\REF2.D Vial: 5 Acq On : 20 Mar 2002 3:04 am Operator: Sample : gc/ms scan 3/5 Inst : GC/MS 209 Mise : Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: Mar 218:362002 <Quant Results File: GCMS0308.RES Quant Method : C:\HPCHEM\1\METHODS\GCMS0308.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Fri Mar 08 08:54:27 2002 Response via : Initial Calibration DataAcq Meth : GCMS0308

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.27 152 656891 20.00 ug/1 -0.08 10) Naphthalene-d8 15.90 136 2602435 20.00 ug/1 -0.09 17) Acenaphthene-diO 21.22 164 1399653 20.00 ug/1 -0.09 29) Phenanthrene-diO 25.66 188 2103404 20.00 ug/1 -0.10 38) Chrysene-dl2 33.72 240 1493208 20.00 ug/1 -0.12 44) Perylene-dl2 37.98 264 1009789 20.00 ug/1 -0.14

System Monitoring Compounds 37) 2,4-DDD 30.73 235 111141 7.27 ug/mL 0.23 Spiked Amount 5.000 Recovery = 145.40%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 5.91 74 115742 5.19 ug/1 # 70 3) bis(2-Chloroethyl)ether 11.65 93 268753 7.49 ug/1 93 4) 1,3-Dichlorobenzene 12.17 146 159610 4.30 ug/1 96 5) 1,4-Dichlorobenzene 12.31 146 172153 4.63 ug/1 99 6) 1,2-Dichlorobenzene 12.83 146 185411 5.35 ug/1 98 7) 2,2'-oxybi s(1-Chloropropan 13.14 45 378486 7.49 ug/1 98 8) N-Nitroso-di-n-propylamine 13.53 70 187361 8.02 ug/1 # 87 9) Hexachloroethane 13.67 117 35107 2.53 ug/1 98 11) Nitrobenzene 13.95 77 250239 7.03 ug/1 93 12) 1sophorone 14.59 82 542658 8.04 ug/1 99 13) bis(2-Chloroethoxy)methane 15.28 93 327235 7.41 ug/1 98 14) 1,2,4-Trichlorobenzene 15.79 180 160698 5.26 ug/1 97 15) Naphthalene 15.96 128 682247 7.09 ug/1 99 16) Hexachlorobutadiene 16.50 225 26751 1.76 ug/1 97 18) Hexachlorocyclopentadiene 18.70 237 14043 1.48 ug/1 100 19) 2-Chloronaphthalene 19.47 162 417122 6.94 ug/1 97 20) Dimethylphthalate 20.56 163 580637 8.24 ug/1 99 21) 2,6-Dinitrotoluene 20.77 165 121726 7.12 ug/1 87 22) Acenaphthylene 20.74 152 676926 7.88 ug/1 99 2 3) Acenaphthene 21.30 153 457339 7.62 ug/1 97 24) 2,4-Dinitrotoluene 21.94 165 160341 7.01 ug/1 # 78 25) Diethylphthalate 22.69 149 565947 8.28 ug/1 96 26) 4-Chlorophenyl-phenylether 22.84 204 232831 7.95 ug/1 93 2 7) Fluorene 22.83 166 511763 8.06 ug/1 100 28) Azobenzen/ 1,2-Diphenylhyd 23.31 77 510017 6.96 ug/L # 85

(#) = qualifier out of range (m) = manual integration REF2.D GCMS0308.M Thu Mar 21 08:39:44 2002 Page 1

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