GCMS analysis report for sample AE01547, March 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\l\5973N\02FEB21\01547 .D Vial: 3 ‘ Acq On : 21 Feb 2002 4:52 pm Operator: Sample : 508 scan Inst : Instrumen Mise : February 21, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\HP022102 .M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 6 Acetic acid, 3-[1,3]dioxola... Concentration Rank 1 R.T. EstConc Area Relative to ISTD R.T. 5.95 0.33 ug/L 131922 1,4-Dichlorobenzene-d4 9.72 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Acetic acid, 3-[1,3]dioxolan-2-y. .. 174 C8H14O4 000000-00-0 38 2 3-(CYCLOHEX-3'-EN-YL)PROPANOL $$ ... 174 C8H14O4 015745-87-6 38 3 2-(3-Bromo-propyl)-[1,3]dioxolane 194 C6HllBrO2 062563-07-9 9 4 Propane, 2-methoxy-2-methyl- (CA... 88 C5H12O 001634-04-4 9 Abundance Scan 228 (5.948 min): 01547.D (-) m/z 73.05 100.00% 73

5000 43 ' ‘ i 1 ' ‘ ‘ I ‘ ‘ ' i • ‘ ' T ‘ ‘ i ‘

miz-> 0- 1. 1.55.. ! 87 1 Tp0mm]mmmpp] 103 :2030405060 70 8090 100110 120 130 140150 160170180190 200 m/z 5.60 5.80 43.10 6.00 6.20 25.77% Abundance: #78238: Acetic acid, 3-[1,3]dioxolan-2-ylpropyl ester 73

5000 ■ ' i ■ ' ■ ■ i ■ ■ ■ ■ i ■ ■ ■ ■ i ■ ■ ‘ ‘ i ■

5.60 5.80 6.00 6.20 43 m/z 45.10 10.18% 27 55 ,। 87 113 174 0- 11 “ ■ ■ i' T Hp TT i■ ।•1111 ‘ । 11111 ■ i ■" ■ i ■ ■" i “ nfc-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #36138: 3-(CYCLOHEX-3'-EN-YL)PROPANOL $$ 2-Cyclohexene-1-p... 73 ■ ■ i ■ ■ 1 1 i 1 1h 1 r1 1 1 1 1 1 11 1 r1 5.60 5.80 6.00 6.20 5000 m/z 41.10 8.90% 43 27 87 113 TpImp 0- ■ i “ " i' , 55 , 174 Tn—m02—0011—0030—m01020002m0mgTmuT m/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #104870:2-(3-Bromo-propyl)-[1,3]dioxolane 73 5.60 5.80 6.00 1 1 i 1 1 ' ■ i 1 6.20 m/z 71.00 7.11% 5000 45

27

m/z—> 0 55 I 85 95 121166 193 j.... I...>t।।. ■ ■ i ■ । । ■ i ■ ■ ■ ■ । ■ < ■ ■ । ■।i■ 20 30-40 50 60 70 80 90 100 110 120 130 140 150160 170 180 190 200 1 ■

5.60 i ' ' 1 ■

5.80 i ■ ■ ■ ■ i

6.00 ■ ■ ■ ■

6.20 i ■ 1 ■ ' i ■

01547.D HP022102.M Mon Feb 25 10:55:25 2002 Page 8

NYC-WTC_000010077