GCMS surrogate recovery results for sample AE00310, Jan 2002

NYC 9/11 Public Portal Document Library Search Compound Report

Data File : C:\MSDCHEM\1\5973N\O2 JAN09\310.D Vial: 8 Acq On : 10 Jan 2002 12:02 am Operator: Sample : 508 scan ext 1/7 Inst : Instrumen Mise : January 9, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\SCAN508.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 3 Acetic acid, 3-[1,3]dioxola... Concentration Rank 1

R.T. EstConc Area Relative to ISTD R.T.

5.89 5.06 ug/L 2435280 1,4-Dichlorobenzene-d4 9.72

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Acetic acid, 3-[1,3]dioxolan-2-y... 174 C8H14O4 000000-00-0 33 2 Butane, 2-methoxy-2-methyl- $$ E... 102 C6H140 000994-05-8 33 3 3-(CYCLOHEX-3'-EN-YL)PROPANOL $$... 174 C8H14O4 015745-87-6 33 4 3-Pentanol, 2,4-dimethyl- 116 C7H16O 000600-36-2 33 Abundance Scan 220 (5.885 min): 310.D (-) m/z 73.10 100.00% 73

5000 43 5.60 5.80 6.00 6.20

m/z-> OPT 20 30 +LRH4 , 87 103 +11—10109PTT 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 i ■ • ■ ■ 111111 ■ ■ ■11 ‘ ■1 ‘ i m/z 43.10 23.77% Abundance #78238: Acetic acid, 3-[1,3)dioxolan-2-ylpropyl ester 73

5000 ...... . l PPurr i|rrn p . . 5.60 5.80 6.00 6.20 43 m/z 45.10 9.60%

m/z--> 27 OT —PPPT 20 30 1 40 55 ■ । • ■ ■ ■ । • > • ■ । ■ 1'' 11 50 60 70 87 113 174 80 90 100 110 120 130 140 150 160 170 180 Abundance #9702: Butane, 2-methoxy-2-methyl- $$ Ether, methyl tert-p... 78 — 5.60 5.80 6.00 6.20 5000 m/z 41.10 8.78% 55 87 27 45

m/z~> 01■ । ■ ■ ■ ■ i ■ -' > i _L __L 4 < >■ ■ i ■■•>।■ ■ . ......... IT i ■ ■ ■ ■ i''1 ■ r ■ " I ■ ■'11'1 ■' i 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 TT Abundance #36138: 3-(CYCLOHEX-3'-EN-YL)PROPANOL $$ 2-Cyclohexene-1-p... 73 5.60 5.80 6.00 6.20 m/z 71.10 6.05% 5000 43 27 55 . 87 113 174 0 ■ r 1 ■ ■ i' TTTT TTTT Tt............... . ■ i' " ' i " 1' i ■1" i1'' ■ i ■ ■ ■ ■ i ■11 ■ 11 111* nimo . . । . /z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 560 5.80 6.00 6.20

310.D SCAN508.M Thu Jan 10 11:52:08 2002 Page 5

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