DEP GCMS data table, Jan-Feb 2002

NYC 9/11 Public Portal Document LlDrary searcn compound Keport

Data File : C:\MSDCHEM\l\5973N\02FEB27\02453.D Vial: 4 • Acq On : 27 Feb 2002 5:47 pm Operator: Sample : 508 scan Inst : Instrumen Mise : February 2 7, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\MSDCHEM\1...\HP022102. M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 8 Pyrimidinetetramine- $$ Pyr... Concentration Rank 7

R.T. EstConc Area Relative to ISTD R.T.

13.39 0.08 ug/L 43487 Naphthalene-d8 13.20

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Pyrimidinetetramine- $$ Pyrimidi... 140 C4H8N6 001004-74-6 78 2 1H,5H-Pyrazolo[1,2-a]pyrazole-1, ... 140 C6H8N2O2 019720-72-0 50 3 4-Cyclopentene-1,3-dione, 4-meth... 140 C7H803 007180-62-3 9 4 4H-Pyran-4-one, 2-ethyl-3-hydrox.. . 140 C7H803 004940-11-8 9 Abundance Scan 887 (13.387 min): 02453. D (-) m/z 140.00 100.00% 14.0

5000 -

44 0! ■ i1 ■ ■ ■ । '11111111111 | 70 86 9 1 13.00 13.20 13.40 13.60 13.80 m/ z 70.00 13.44% m/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 Abundance #35040: Pyrimidinetetramine- $$ Pyrimidine, 2,4,5,6-tetraa... VO

5000 1 i 1 -11 - 1 ' । । 1 ' । । । 13.00 13.20 13.40 13.60 13.80 44 71 123 m/z 66.00 12.88% ,I 86 96 112 |i | itrn।iii[। । i i । । ।iii।iiii।oiilr m/z-> OP ■ 1 । । 1 । । । I — 20 30 40 50 -r-p-r-r-r-p-r 60 70 80 90 100 110 120 130 140 4l Abundance #35166:1 H,5H-Pyrazolo[1 ,2-a]pyrazole-1 ,5-dione, tetrahydro- VO

55 13.00 13.20 13.40 13.60 13.80 5000 m/z 141.10 12.81% 42 98 27 70 86 112 - I 01 1 1 ' 1 1 ' i ' ' ' ' i ■ 1 । 1 1 T-p-r Ii - ' 1 I mfe-> 20 30 40 50 60 70 80 90 100 110 120 130 140 Abundance #35333: 4-Cyclopentene-1,3-dione, 4-methoxy-5-methyl- 83 VO 13.00 13.20 13.40 13.60 13.80 m/ z 86.10 10.61%

5000

59 70 97 111 0 _ __________ ।___ I ----- ' i1 ■ ' ■ i 1' ■ ■ i ■ ■'' i ■ ■ ■ ■ i ■ ■ ■ ■ 1' ' i 125 ' i 1 ' I wW. AWNMPA/ m/z-> 20 30 40 50 60 70) 80 90 100 110 120 130 140 13.00 13.20 13.40 13.60 13.80

92453.D HP022102.M Thu Feb 28 08:47:23 2002 Page 10

NYC-WTC_000005079