GCMS analysis results for sample AE00841, Feb 26 2002

NYC 9/11 Public Portal Document

Data File : C:\MSDCHEM\1\5973N\02FEB07\00841.D Vial: 4 Acq On : 7 Feb 2002 1:32 pm Operator: Sample : 508 scan Inst : Instrumen Mise : February 7, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\MSDCHEM\l-..\HP020702.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 9 Pyrimidinetetramine- $$ Pyr... Concentration Rank 12

R.T. EstConc Area Relative to ISTD R.T.

13.38 0.06 ug/L 39167 Naphthalene-d8 13.19

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Pyrimidinetetramine- $$ Pyrimidi... 140 C4H8N6 001004-74-6 72 2 2-Methoxy-3-hydrazinyl-pyrazine 140 C5H8N40 000000-00-0 40 3 4-Cyclopentene-1,3-dione, 4-meth... 140 C7H8O3 007180-62-3 9 4 Cyclobuta [de] naphthalene 140 C11H8 024973-91-9 9 Abundance Scan 876 (13.375 min): 00841 .D (-) m/z 140.10 100.00% 140

5000

54 70 86 96 13.00 13.20 13.40 13.60 13.80

m/z-> 30 °h 40 50 60 70 80 90 100 4 110 120 130 140 m/Z 96.10 13.64% Abundance #35040: Pyrimidinetetramine- $$ Pyrimidine, 2,4,5,6-tetraa... VO

5000 ■ । ■ ■ ■ ■ । ■ ■ ■ i ■ ■ ■ ■ । ’ ■ ■ 1 । 1 13.00 13.20 13.40 13.60 13.80 44 71 123 m/z 141.10 13.30%

m/z-> Oh 30I 1 1 . । । । । । । । ।

40 50 60 470 -- 80 86 96 112 90 100 110 120 130 140 TIm-

Abundance #35089: 2-Methoxy-3-hydrazinyl-pyrazine 14.0 —- 13.00 13.20 13.40 13.60 13.80 5000 42 m/ Z 94.10 11.94% 54 68 80 95 108 121

m/z—> 0 i PT 30 40 ' 1 I 1 50 1 1 1 1 ' 60 . 80I..90 in.. 70 J'.. 100 110 120 130 | | 140 Abundance #35333: 4-Cyclopentene-1,3-dione, 4-methoxy-5-methyl- ■ i 1 1 .q.. 83 VO 13 00 13.20 13.40 13.60 13.80 m/z 70.00 11.82%

5000

70

n/z-> Ob 30 _______________ i < I > i ' ■ i • ■ ■ ■ i • 40 50 59 60 — 70 80 +111—12— +L 90 100 110 120 130 140 ....... 13.00 13.20 13.40 13.60 13.80

00841.D HP020702.M Thu Feb 21 09:58:03 2002 Page 11

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