DEP GCMS data table, Jan-Feb 2002

NYC 9/11 Public Portal Document Library searen compound Keport

Data File : C:\MSDCHEM\1\5973N\02FEB27\02453.D Vial: 4 Acq On : 27 Feb 2002 5:47 pm Operator: Sample : 508 scan Inst : Instrumen Mise : February 27, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\MSDCHEM\1...\HP022102.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 7 Acetic acid, 3-[1,3]dioxola... Concentration Rank 2 R.T. EstConc Area Relative to ISTD R.T. 5.95 0.30 ug/L 118196 1,4-Dichlorobenzene-d4 9.72 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Acetic acid, 3-[1,3]dioxolan-2-y... 174 C8H14O4 000000-00-0 28 2 3-(CYCLOHEX-3’-EN-YL)PROPANOL $$.. . 174 C8H14O4 015745-87-6 28 3 N-Ethylformamide $$ N-Formylethy... 73 C3H7NO 000627-45-2 9 4 2-Thiabicyclo[3.1.0]hex-3-ene-6-. . . 184 C9H1202S 056666-52-5 9 Abundance Scan 228 (5.948 min): 02453.D (-) m/z 73.00 100.00% 73

5000 43

55 5.60 5.80 6.00 6.20 o11 ‘ i111 ■ i ■ । — i ■1" II, 11 ‘1 '''i ■ ■ ■111 Tg 103 87 OOTTTETTIT m/ z 43.10 25.34% n/z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 Abundance #78238: Acetic acid, 3-[1,3]dioxolan-2-ylpropyl ester 73 N 5000 ■ 1 i 1 ■ ‘ i 1 ' ' ' i ■ ' 1 i 1 ' 1 1 I ' 5.60 5.80 6.00 6.20 43 m/z 45.10 9.97% 27 55 , 87 113 174 0- TITTTTTTT ‘1‘*‘‘1‘‘41, 1। ' 1assalt1sssastos*od1ase2ssI2**1//1*** miz-> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 Abundance #36138: 3-(CYCLOHEX-3'-EN-YL)PROPANOL $$ 2-Cyclohexene-1-p... 73

5.60 m/z 5.80 41.10 m 6.00 6.20 8.95% 5000

43 27 0- TTTr ' r55‘ " r ‘' ■ i ■ 11111187ii ■ " ' i " " 113 174 i " " i " '11" 111" " i " 1' i " " i' ‘ " i' rn/z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 Abundance #1794: N-Ethylformamide $$ N-Formylethylamine $$ Formamide... 30 5.60 5.80 6.00 6.20 73 m/z 71.10 4.83%

5000 44 58

15

m/z-> 0 I' । | I I1! I | I ! I1, rasligans i " 1 1 i'1 1 " । " 1 1 । 1 ' 1 1 i r ■ ■ ■ । 1 ■ 1 1 i ■ ■ 1 ■ i 1 ' । 1 । 1 1 ' ' । 1 ■ ■ ‘ । 1 । ' 1 । 1 ■ ■ ■ । 1 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 5.60 5.80 6.00 6.20

02453.D HP022102.M Thu Feb 28 08:47:23 2002 Page 9

NYC-WTC_000005078