GCMS analysis results for sample AE00472, Feb 26 2002

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Data File : C:\MSDCHEM\l\5973N\02FEB07\00472A.D Vial: 3 Acq On : 7 Feb 2002 12:42 pm Operator: Sample : 508 scan re-ext. Inst : Instrumen Mise : February 7, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\HP020702.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N. L ********************************************************************* Peak Number 6 Acetic acid, 3-[1,3]dioxola... Concentration Rank 2

R.T. EstConc Area Relative to ISTD R.T.

5.92 0.46 ug/L 202328 1,4-Dichlorobenzene-d4 9.71

Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Acetic acid, 3-[1,3]dioxolan-2-y... 174 C8H14O4 000000-00-0 42 2 3-(CYCLOHEX-3'-EN-YL)PROPANOL $$... 174 C8H14O4 015745-87-6 42 3 Butane, 2-methoxy-2-methyl- 102 C6H140 000994-05-8 36 4 Butane, 2-methoxy-2-methyl- $$ E... 102 C6H140 000994-05-8 36 Abundance Scan 223 (5.920 min): 00472A.D (-) m/ z 73.10 100.00% 73

n/z-> 5000

Abundance 0 ■ i’ "’’ir 20 30 43

—ll1 Trt 40 55 Ll ’m’i T"f 50 60 70 ...... .... ...... . 80 90 100 110 120 130 140 150 160 170 180 #78238: Acetic acid, 3-[1,3]dioxolan-2-ylpropyl ester 5.60 m/ Z £ 5.80 43.10 6.00 6.20 24.81%

73

5000 I ”1 r7 TT I”t ITSrr TPr I AM n 5.60 5.80 6.00 6.20 43 m7z 41.10 10.53% 27 55 . 87 113 174 0 ■ l > >1 -11 . i. (11.11 I I'l I 11 11 l'pJ ) 1 r ■ ■ ■ i " r " ' i ■ ■ ■ ■ i ■ ■ ■ ■ i'1 ■ ■ i i1 ‘ ■11 • m/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 Abundance #36138: 3-(CYCLOHEX-3'-EN-YL)PROPANOL $$ 2-Cyclohexene-1-p... 70 — Pfr A ’ i * * ' • i 5.60 5.80 6.00 6.20 5000 m/z 45.10 8.46% 43

m/z-> o1 20 1112...si 30 40 55 ., 87 PVP—nt P1]T MT 113 I'1 ■ ■ r • ■ ■ i ■1'' I'' " i ■ " ' i 501 60 70 80 90 100 110 120 130 140 150 160 170 180 174 i ■ •1 ■ ।1

Abundance #9701: Butane, 2-methoxy-2-methyl- 73 5.60 5.80 6.00 6.20 m/z 71.10 7.94%

5000 55 87 27 45

m/z-> 0- L 20 30 40 50 60 70 +011—110010IIIPTTTTTT 80 90 100 110 120 130 140 150 160 170 180 TT 5 60 5.80 6.00 6.20 T

00472A.D HP020702.M Thu Feb 21 09:57:54 2002 Page 8

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