GCMS DFTPP calibration report, Feb 5 2002

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■ Data File : C:\MSDCHEM\1\5973N\02FEB05\00003A.D Vial: 2 Acq On 5 Feb 2002 3:46 pm Operator: Sample : 508 scan; re-ext Inst : Instrumen Mise : February 5, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\HP020702.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ************* * * ****************************************************** Peak Number 11 4-METHOXY-.BETA.-METHYLCINN... Concentration Rank 5

R.T. EstConc Area Relative to ISTD R.T.

22.28 0.17 ug/L 206220 Phenanthrene-dl0 22.65

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 4-METHOXY-.BETA.-METHYLCINNAMIC ... 192 C11H1203 019169-94-9 72 2 Phenanthrene, 9-methyl- $$ 9-Met... 192 C15H12 000883-20-5 64 3 3-Cyanocarbazole $$ 9H-Carbazole... 192 C13H8N2 057102-93-9 64 4 Phenanthrene, 1-methyl- 192 C15H12 000832-69-9 53 Abundance Scan 1656 (22.280 min): 00003A.D (-) m/z 192.10 100.00% 192

5000

42 54 66 82 96 , 146 160 120 !) I I I I | I r | I I I rp I , . | . . . . | I , . I |" II A 22.00 22.20 22.40 22.60 0 TTTT '111 ■■ i ‘111 j... 111 ■ 1. । —TTTT Tiijn m/z 96.10 19.13% n/z-> 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #102588: 4-METHOXY-.BETA.-METHYLCINNAMIC ACID $$ 2-Butenoi... 192

108 5000- 22.00 22.20 22.40 22.60 146 175 m/z 193.10 13.72%

0 1111111)113P—000V0BBB—"IT""‘rI‘T ‘111111111‘‘‘1b i “ * n ■1 * 'T1 + n/z-> 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #103936: Phenanthrene, 9-methyl- $$ 9-Methylphenanthrene 19 2 -r-r-p-r ■ ' I ■ 22.00 22.20 22.40 22.60 5000 m/z 146.10 13.69%

96 TDTTTTTT 4 165

n/z-> 0 88 J + 176 139 152 I " ' rl " 1 ''111 " I'1111111111 ilt > f. >.. j • ■ ।. j. 11. । ■»> |_| 11 ■ ■ 11 ■ 111 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #103424:3-Cyanocarbazole $$ 9H-Carbazole-3-carbonitrile (CAS 0 192 22.00 22.20 22.40 22.60 m/z 191.10 13.66%

5000

164 96

/z-> 138 0 "‘0‘110T060606T00770167 ‘0‘ -----PPTTP 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Ll 1 ■ i ■ ■ n.....a 22.00 22.20 22.40 22.60

00003A.D SCAN508.M Thu Feb 21 10:18:51 2002 Page 13

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